Kinetics of homogeneous acetoxylation of cyclododecene and 1,5,9-cyclododecatriene catalyzed by Pd(OAc)2

被引:3
|
作者
Balbolov, E [1 ]
Dimitrov, SD
机构
[1] Zlatarov Univ, Dept Organ Synth, Bourgas 8010, Bulgaria
[2] Zlatarov Univ, Dept Chem Engn, Bourgas 8010, Bulgaria
来源
关键词
acetoxylation; Pd(OAc)(2); cyclododecene; 1,5,9-cyclododecatriene;
D O I
10.1007/BF02475468
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The kinetics of acetoxylation of cyclododecene and (E,E,E)-1,5,9-cyclododecatriene catalyzed by Pd(OAc)(2) has been studied in glacial acetic acid solutions at 323-343 K and atmospheric pressure. The experimental data were described by kinetic equations of the Michaelis - Menten type.
引用
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页码:305 / 311
页数:7
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