Metal-free oxidative cross-coupling of diazirines with arylboronic acids

被引：13

作者：

Wu, Guojiao ^{[1
]}

Zhao, Xia ^{[1
,2
]}

Ji, Wenzhi ^{[1
]}

Zhang, Yan ^{[1
]}

Wang, Jianbo ^{[1
]}

机构：

[1] Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China

[2] Tianjin Normal Univ, Coll Chem, Tianjin Key Lab Struct & Performance Funct Mol, Tianjin 300387, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 09期

关键词：

ALPHA-DIAZOCARBONYL COMPOUNDS; CARBENE MIGRATORY INSERTION; H BOND FUNCTIONALIZATION; ORGANOBORON COMPOUNDS; CATALYZED REACTIONS; BORONIC ACIDS; ARYL HALIDES; 1,1-DIARYLETHYLENES; TOSYLHYDRAZONES; SULFONYLHYDRAZONES;

D O I：

10.1039/c5cc08855k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report herein a metal-free cross-coupling of diazirines with arylboronic acids under oxidative conditions. The reaction affords a series of substituted olefins. It is proposed that the interaction between the nitrogen on diazirine with arylboronic acid plays a key role in this transformation.

引用

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页码：1961 / 1963

页数：3

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