Crystal structure of a novel phenolato, azido, and acetato co-bridged trinuclear zinc(II) complex derived from 4-chloro-2-[(2-diethylaminoethylimino)methyl]phenol

被引：4

作者：

Sheng, G. -H. ^{[1
]}

Cheng, X. -S. ^{[2
]}

You, Z. -L. ^{[2
]}

Zhu, H. -L. ^{[1
]}

机构：

[1] Shandong Univ Technol, Sch Life Sci, Zibo, Shandong, Peoples R China

[2] Liaoning Normal Univ, Dept Chem & Chem Engn, Dalian, Peoples R China

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 55卷 / 06期

关键词：

Schiff base; trinuclear complex; zinc complex; crystal structure; X-ray crystallography; COPPER(II);

D O I：

10.1134/S002247661406016X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel phenolato, azido, and acetato co-bridged trinuclear zinc(II) complex [Zn3L2(mu(2)-CH3COO)(2) (mu(1,1)-N-3)(N-3)], where L is the deprotonated form of 4-chloro-2-[(2-diethylaminoethylimino)methyl]phenol, is prepared and characterized by elemental analysis, infrared spectrum, and single crystal X-ray determination. The complex crystallizes in the triclinic space group , with unit cell dimensions a = 12.7196(5) , b = 13.6597(6) , c = 13.7214(5) , alpha = 65.700(1)A degrees, beta = 83.429(1)A degrees, gamma = 63.545(1)A degrees, V = 1938.4(1) (3), Z = 2, GOOF = 1.013, R (1) = 0.0456, and wR (2) = 0.1032. Structural analysis shows that the distances among the adjacent zinc atoms are 3.282(1) and 3.213(1) . The zinc atoms are in distorted square pyramidal and trigonal bipyramidal coordinations.

引用

页码：1106 / 1110

页数：5

共 50 条

[21] Synthesis, crystal structures, and antimicrobial activity of two thiocyanato-bridged dinuclear copper(II) complexes derived from 2,4-dibromo-6-[(2-diethylaminoethylimino)methyl]phenol and 4-nitro-2-[(2-ethylaminoethylimino)methyl]phenol
Hong, Zhe
TRANSITION METAL CHEMISTRY, 2008, 33 (06) : 797 - 802
[22] Synthesis, crystal structures, and antimicrobial activity of two thiocyanato-bridged dinuclear copper(II) complexes derived from 2,4-dibromo-6-[(2-diethylaminoethylimino)methyl]phenol and 4-nitro-2-[(2-ethylaminoethylimino)methyl]phenol
Zhe Hong
Transition Metal Chemistry, 2008, 33 : 797 - 802
[23] Synthesis, Crystal Structures and Antifungal Activities of Two Isostructural Dinuclear Zinc(II) Complexes Derived from 4-Chloro-2-[(2-methylaminoethylimino)methyl]phenol
Li, Z. -P.
Li, Y-J.
Shi, A. -H.
Ouyang, Y. -Z.
POLISH JOURNAL OF CHEMISTRY, 2009, 83 (01) : 31 - 38
[24] A Rarely Seen Phenolato and Azido-Bridged Polymeric Cadmium(II) Complex Derived from 2-Bromo-6-[(2-isopropylaminoethylimino)methyl] phenol
Cheng, Guo-Ping
Xue, Ling-Wei
Zhang, Cai-Xia
ACTA CHIMICA SLOVENICA, 2017, 64 (01) : 261 - 265
[25] Synthesis and crystal structures of cobalt(III) and zinc(II) complexes derived from 4-chloro-2-[(2-morpholin-4-ylethylimino)methyl]phenol with urease inhibitory activity
Wang, C. Y.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2010, 36 (03) : 177 - 182
[26] Synthesis and crystal structures of cobalt(III) and zinc(II) complexes derived from 4-chloro-2-[(2-morpholin-4-ylethylimino)methyl]phenol with urease inhibitory activity
C. Y. Wang
Russian Journal of Coordination Chemistry, 2010, 36 : 177 - 182
[27] Crystal structure of 4-chloro-2-{(E)-[(3,4-dimethylphenyl)imino]methyl}phenol
Salim, Muhammad
Tahir, Muhammad Nawaz
Munawar, Munawar Ali
Shahid, Muhammad
Shad, Hazoor Ahmad
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O416 - U354
[28] Synthesis and crystal structures of two Schiff base copper(II) complexes derived from 4-chloro-2-[(2-morpholin-4-ylethylimino)methyl]phenol
Y. L. Sang
X. S. Lin
Russian Journal of Coordination Chemistry, 2010, 36 : 472 - 476
[29] Synthesis and crystal structures of two Schiff base copper(II) complexes derived from 4-chloro-2-[(2-morpholin-4-ylethylimino)methyl]phenol
Sang, Y. L.
Lin, X. S.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2010, 36 (06) : 472 - 476
[30] Anion-controlled syntheses and crystal structures of a pair of novel azide-bridged copper(II) complexes constructed from 4-chloro-2-[(2-dimethylaminoethylimino)methyl]phenol
You, Zhong-Lu
Jiao, Qing-Zhu
Niu, Shu-Yun
Chi, Jing-Yun
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (15): : 2481 - 2485

← 1 2 3 4 5 →