Crystal structure of a novel phenolato, azido, and acetato co-bridged trinuclear zinc(II) complex derived from 4-chloro-2-[(2-diethylaminoethylimino)methyl]phenol

被引：4
|
作者：
Sheng, G. -H. [1 ]
Cheng, X. -S. [2 ]
You, Z. -L. [2 ]
Zhu, H. -L. [1 ]
机构：
[1] Shandong Univ Technol, Sch Life Sci, Zibo, Shandong, Peoples R China
[2] Liaoning Normal Univ, Dept Chem & Chem Engn, Dalian, Peoples R China
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 55卷 / 06期
关键词：
Schiff base; trinuclear complex; zinc complex; crystal structure; X-ray crystallography; COPPER(II);
D O I：
10.1134/S002247661406016X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel phenolato, azido, and acetato co-bridged trinuclear zinc(II) complex [Zn3L2(mu(2)-CH3COO)(2) (mu(1,1)-N-3)(N-3)], where L is the deprotonated form of 4-chloro-2-[(2-diethylaminoethylimino)methyl]phenol, is prepared and characterized by elemental analysis, infrared spectrum, and single crystal X-ray determination. The complex crystallizes in the triclinic space group , with unit cell dimensions a = 12.7196(5) , b = 13.6597(6) , c = 13.7214(5) , alpha = 65.700(1)A degrees, beta = 83.429(1)A degrees, gamma = 63.545(1)A degrees, V = 1938.4(1) (3), Z = 2, GOOF = 1.013, R (1) = 0.0456, and wR (2) = 0.1032. Structural analysis shows that the distances among the adjacent zinc atoms are 3.282(1) and 3.213(1) . The zinc atoms are in distorted square pyramidal and trigonal bipyramidal coordinations.
引用
收藏
页码：1106 / 1110
页数：5
相关论文
共 50 条
12345