Spray coating of dense proton-conducting BaCe0.7Zr0.1Y0.2O3 electrolyte for low temperature solid oxide fuel cells

In this work, we report the spray coating, a simple and effective method, to prepare proton conducting BaCe0.7Zr0.1Y0.2O3 (BCZY) membranes on the pre-annealed porous anode substrates. The effects of sintering temperature on the electrolyte membrane and anode microstructure, proton conductivities of the resulted thin films, and their fuel cell performances in H-2/air were investigated. Dense BCZY membranes with improved anode microstructure and good proton conductivity have been successfully obtained at reduced temperature using ZnO sintering aid. SOFCs using spray-coated electrolyte thin films gave a stable OCV value of 1.03 V and a maximum power density of 362 mW cm(-2) at 650 degrees C when operated using hydrogen as fuel and air as the oxidant. Copyright (C) 2016, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.