Sustainable Cyclic Carbonate Production, Utilizing Carbon Dioxide and Azolate Ionic Liquids

被引：82
|
作者：
Goodrich, Peter [1 ]
Gunaratne, H. Q. Nimal [1 ]
Jacquemin, Johan [1 ]
Jin, Lili [1 ,2 ]
Lei, Yuntao [1 ,2 ]
Seddon, Kenneth R. [1 ]
机构：
[1] Queens Univ Belfast, Sch Chem & Chem Engn, QUILL Res Ctr, Stranmillis Rd, Belfast BT9 5AG, Antrim, North Ireland
[2] China Pharmaceut Univ, Sch Sci, 639 Longmian Rd, Nanjing 210009, Jiangsu, Peoples R China
来源：
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2017年 / 5卷 / 07期
关键词：
Green chemistry; Azolate ionic liquids; Recyclable catalysts; Epoxides; Cyclic carbonates; N-HETEROCYCLIC CARBENES; CO2; FIXATION; EFFICIENT CATALYST; CHEMICAL FIXATION; COUPLING REACTION; OXALYL CHLORIDE; EPOXIDES; CYCLOADDITION; TRANSFORMATION; TEMPERATURE;
D O I：
10.1021/acssuschemeng.7b00355
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient protocol is described for producing cyclic carbonates in good to excellent yields under moderate reaction conditions (100.0 degrees C, 1.0 MPa) by treating epoxides with carbon dioxide, promoted by a series of azolate ionic liquids, which are effective, recyclable, metal-free, and halide-free catalysts.
引用
下载
收藏
页码：5635 / 5641
页数：7
相关论文
共 50 条
  • [21] Efficient synthesis of cyclic carbonate from carbon dioxide using polymer anchored diol functionalized ionic liquids as a highly active heterogeneous catalyst
    Watile, Rahul A.
    Deshmukh, Krishna M.
    Dhake, Kishor P.
    Bhanage, Bhalchandra M.
    CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (05) : 1051 - 1055
  • [22] Sustainable functionalization of cellulose and starch with diallyl carbonate in ionic liquids
    Soeyler, Zafer
    Meier, Michael A. R.
    GREEN CHEMISTRY, 2017, 19 (16) : 3899 - 3907
  • [23] Catalytic applications of immobilized ionic liquids for synthesis of cyclic carbonates from carbon dioxide and epoxides
    Kim, Dong-Woo
    Roshan, Roshith
    Tharun, Jose
    Cherian, Amal
    Park, Dae-Won
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2013, 30 (11) : 1973 - 1984
  • [24] Catalytic applications of immobilized ionic liquids for synthesis of cyclic carbonates from carbon dioxide and epoxides
    Dong-Woo Kim
    Roshith Roshan
    Jose Tharun
    Amal Cherian
    Dae-Won Park
    Korean Journal of Chemical Engineering, 2013, 30 : 1973 - 1984
  • [25] Hydrogensulphate ionic liquids as an efficient catalyst for the synthesis of cyclic carbonates from carbon dioxide and epoxides
    Jasiak, Katarzyna
    Siewniak, Agnieszka
    Kopczyliska, Katarzyna
    Chrobok, Anna
    Baj, Stefan
    JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2016, 91 (11) : 2827 - 2833
  • [26] Carbon Dioxide Utilisation for the Synthesis of Unsymmetrical Dialkyl and Cyclic Carbonates Promoted by Basic Ionic Liquids
    Goodrich, Peter
    Gunaratne, H. Q. Nimal
    Jin, Lili
    Lei, Yuntao
    Seddon, Kenneth R.
    AUSTRALIAN JOURNAL OF CHEMISTRY, 2018, 71 (2-3) : 181 - 185
  • [27] Design and synthesis of pyridinamide functionalized ionic liquids for efficient conversion of carbon dioxide into cyclic carbonates
    Lei, Yuntao
    Gunaratne, H. Q. Nimal
    Jin, Lili
    JOURNAL OF CO2 UTILIZATION, 2022, 58
  • [28] Bifunctional Ionic Liquids Derived from Biorenewable Sources as Sustainable Catalysts for Fixation of Carbon Dioxide
    Saptal, Vitthal B.
    Bhanage, Bhalchandra M.
    CHEMSUSCHEM, 2017, 10 (06) : 1145 - 1151
  • [29] Insights into Carbon Dioxide Electroreduction in Ionic Liquids: Carbon Dioxide Activation and Selectivity Tailored by Ionic Microhabitat
    Feng, Jianpeng
    Zeng, Shaojuan
    Liu, Huizhen
    Feng, Jiaqi
    Gao, Hongshuai
    Bai, Lu
    Dong, Haifeng
    Zhang, Suojiang
    Zhang, Xiangping
    CHEMSUSCHEM, 2018, 11 (18) : 3191 - 3197
  • [30] Concept of Utilizing Ionic Liquids for the Co-Electroreduction of Carbon Dioxide and Nitrogen-Containing Compounds
    Dongare, Saudagar
    Coskun, Oguz Kagan
    Gurkan, Burcu
    CHEMCATCHEM, 2024,
12345