Sustainable Cyclic Carbonate Production, Utilizing Carbon Dioxide and Azolate Ionic Liquids

被引：82
|
作者：
Goodrich, Peter [1 ]
Gunaratne, H. Q. Nimal [1 ]
Jacquemin, Johan [1 ]
Jin, Lili [1 ,2 ]
Lei, Yuntao [1 ,2 ]
Seddon, Kenneth R. [1 ]
机构：
[1] Queens Univ Belfast, Sch Chem & Chem Engn, QUILL Res Ctr, Stranmillis Rd, Belfast BT9 5AG, Antrim, North Ireland
[2] China Pharmaceut Univ, Sch Sci, 639 Longmian Rd, Nanjing 210009, Jiangsu, Peoples R China
来源：
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2017年 / 5卷 / 07期
关键词：
Green chemistry; Azolate ionic liquids; Recyclable catalysts; Epoxides; Cyclic carbonates; N-HETEROCYCLIC CARBENES; CO2; FIXATION; EFFICIENT CATALYST; CHEMICAL FIXATION; COUPLING REACTION; OXALYL CHLORIDE; EPOXIDES; CYCLOADDITION; TRANSFORMATION; TEMPERATURE;
D O I：
10.1021/acssuschemeng.7b00355
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient protocol is described for producing cyclic carbonates in good to excellent yields under moderate reaction conditions (100.0 degrees C, 1.0 MPa) by treating epoxides with carbon dioxide, promoted by a series of azolate ionic liquids, which are effective, recyclable, metal-free, and halide-free catalysts.
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页码：5635 / 5641
页数：7
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