1H NMR study of the hydrolysis of N-acylhydroxy[2H]methylpyrroles

被引：10

作者：

Abell, AD ^{[1
]}

Litten, JC ^{[1
]}

Nabbs, BK ^{[1
]}

机构：

[1] Univ Canterbury, Dept Chem, Christchurch 1, New Zealand

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 08期

关键词：

D O I：

10.1039/a801276h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

KOH catalysed hydrolysis of the (S)- and (R)-N-(N-phthalylleucinyl)hydroxy[H-2]methylpyrroles 6b and 6c, in CD3CN containing 1 equiv. of (+)-sec-butylamine, proceeds by an initial N- to O-acyl transfer with retention of configuration at the labelled centre, followed by trapping of an azafulvene to give (S)- and (R)-sec-butylamino[H-2]methylpyrroles 9b.

引用

页码：919 / 920

页数：2

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