2D covalent organic frameworks with built-in amide active sites for efficient heterogeneous catalysis

被引:46
|
作者
Li, Yang [1 ]
Chen, Weiben [1 ]
Gao, Ruidong [1 ]
Zhao, Ziqiang [1 ]
Zhang, Ting [1 ]
Xing, Guolong [1 ]
Chen, Long [1 ]
机构
[1] Tianjin Univ, Dept Chem, Tianjin Key Lab Mol Optoelect Sci, Sch Sci, Tianjin 300072, Peoples R China
基金
中国国家自然科学基金;
关键词
SELECTIVE SORPTION; CO2; POLYMER; CONVERSION; CAPTURE;
D O I
10.1039/c9cc07500c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Benzene-1,3,5-tricarboxamides (BTAs) are versatile building blocks for supramolecular assembly due to the strong intermolecular hydrogen bonding. Herein, a BTA based amine, N-1,N-3,N-5-tris(4-aminophenyl)benzene-1,3,5-tricarboxamide (TABTA), was successfully applied to construct two new amide functionalized covalent organic frameworks (COFs) with apparent crystallinity, which were further applied as efficient catalysts for Knoevenagel condensation.
引用
收藏
页码:14538 / 14541
页数:4
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