2D covalent organic frameworks with built-in amide active sites for efficient heterogeneous catalysis

被引：46

作者：

Li, Yang ^{[1
]}

Chen, Weiben ^{[1
]}

Gao, Ruidong ^{[1
]}

Zhao, Ziqiang ^{[1
]}

Zhang, Ting ^{[1
]}

Xing, Guolong ^{[1
]}

Chen, Long ^{[1
]}

机构：

[1] Tianjin Univ, Dept Chem, Tianjin Key Lab Mol Optoelect Sci, Sch Sci, Tianjin 300072, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 96期

基金：

中国国家自然科学基金;

关键词：

SELECTIVE SORPTION; CO2; POLYMER; CONVERSION; CAPTURE;

D O I：

10.1039/c9cc07500c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Benzene-1,3,5-tricarboxamides (BTAs) are versatile building blocks for supramolecular assembly due to the strong intermolecular hydrogen bonding. Herein, a BTA based amine, N-1,N-3,N-5-tris(4-aminophenyl)benzene-1,3,5-tricarboxamide (TABTA), was successfully applied to construct two new amide functionalized covalent organic frameworks (COFs) with apparent crystallinity, which were further applied as efficient catalysts for Knoevenagel condensation.

引用

页码：14538 / 14541

页数：4

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