Effects of Mn doping on electrical properties of BiFeO3-SrTiO3 solid solution

被引:10
|
作者
Hai, Liangwen [1 ]
Liu, Hongbo [1 ]
机构
[1] Shanghai Univ Engn Sci, Sch Mat Engn, Shanghai 201620, Peoples R China
基金
中国国家自然科学基金; 上海市自然科学基金;
关键词
BiFeO3; SrTiO3; Mn-doping; Electrical energy storage; HIGH-ENERGY DENSITY; DIELECTRIC PERMITTIVITY; DEGRADATION; CAPACITORS; BREAKDOWN;
D O I
10.1016/j.ssc.2022.114652
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
30BiFeO(3)-70SrTiO(3) ceramic is a novel dielectric material with high permittivity and a low-temperature coefficient of capacitance at high temperatures. To reduce its dielectric loss, Mn doping was performed. The relation between the doping quantity of Mn and the electrical properties of 30BiFeO(3)-70SrTiO(3) ceramics were studied comprehensively. A general rule of Mn doping for ceramics with Fe elements is proposed. The optimized doping concentration is 1%, which reduces dielectric loss and leakage current simultaneously. Under a moderate electric field of 150 kV/cm, the energy storage density of 1% (mole) Mn-doped 30BiFeO(3)-70SrTiO(3) is 1.86 J/cm(3) and the efficiency is 0.70. These results indicate that Mn-doped 30BiFeO(3)-70SrTiO(3) ceramic is a promising candidate for electrical energy storage applications at high temperatures.
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页数:5
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