Self-assembly of a novel manganiferous coordination polymer with mixed ligands

被引:18
|
作者
Yao, YW
Cai, Q
Kou, HZ
Li, HD
Wang, D [1 ]
Yu, RB
Chen, YF
Xing, XR
机构
[1] Chinese Acad Sci, Inst Proc Engn, Beijing 100080, Peoples R China
[2] Tsing Hua Univ, Dept Mat Sci & Engn, Beijing 100080, Peoples R China
[3] Univ Sci & Technol Beijing, Dept Phys Chem, Beijing 100083, Peoples R China
关键词
D O I
10.1246/cl.2004.1270
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel coordination polymer, [(NA)(ONA) Mn(II)](n) (HNA = nicotinic acid; H(2)ONA = 2-hydroxynicotinic acid) has been hydrothermally synthesized. Its structure is constructed by mixed-ligands and chains of hexa-coordinated Mn(II) linkers: ONA groups bridge Mn ions to give the right-handed and left-handed helical [(ONA)Mn](n) chains running along (010). The helical chains are further held together by NA groups to form a novel 3-D framework.
引用
收藏
页码:1270 / 1271
页数:2
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