Mechanical properties of silicone rubber composed of diverse vinyl content silicone gums blending

被引:129
|
作者
Xu, Qiang [1 ]
Pang, Minglei [1 ]
Zhu, Lixia [1 ]
Zhang, Yuanyuan [1 ]
Feng, Shengyu [1 ]
机构
[1] Shandong Univ, Key Lab Special Funct Aggregated Mat, Minist Educ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
基金
中国国家自然科学基金;
关键词
Siloxane polymer matrix; Mechanical; Elastic behavior; CROSS-LINKING; POLYDIMETHYLSILOXANE; REINFORCEMENT; ELASTOMERS; VULCANIZATION; CONDUCTIVITY; NETWORKS; AGENT; DMA;
D O I
10.1016/j.matdes.2010.04.052
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Silicone rubber composed of diverse vinyl content silicone gums blending were prepared and their mechanical properties were investigated. The silicone rubber composed of diverse vinyl content silicone gums blending whose crosslinking points were concentration distribution exhibited better tearing strength and higher tensile modulus in comparison with single vinyl content gums which were mean distribution. The average molecular weight (Mc) of the silicone rubber composed of diverse vinyl content blending are lower than that of single vinyl molar content 0.16% which was calculated by swelling equilibrium method. The viscoelastic behavior indicated the silicone rubber composed of 0.04% and 0.3% vinyl molar content gums blending possessed perfect flexibility at low temperature because it had the lowest glass transition temperature (T-g), and this sample had the largest storage modulus and loss modulus. (C) 2010 Elsevier Ltd. All rights reserved.
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页码:4083 / 4087
页数:5
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