Rechargeable Li-Air Batteries with Carbonate-Based Liquid Electrolytes

被引：352
|
作者：
Mizuno, Fuminori [1 ]
Nakanishi, Shinji [1 ]
Kotani, Yukinari [1 ]
Yokoishi, Shoji [1 ]
Iba, Hideki [1 ]
机构：
[1] Toyota Motor Co Ltd, Battery Res Div, Higashifuji Tech Ctr, Shizuoka 4101193, Japan
来源：
ELECTROCHEMISTRY | 2010年 / 78卷 / 05期
关键词：
Li-Air Battery; Rechargeablility; Air Cathode; Li2O2; LITHIUM; OXYGEN;
D O I：
10.5796/electrochemistry.78.403
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Rechargeable Li-air battery is a candidate for post Li-ion battery with high energy density. In this paper, the rechargeability of Li-air battery over 100 cycles was confirmed and its capacity retention over 60% was achieved. Nevertheless, a large voltage gap between the discharge-charge profiles was observed. Here, a discharged product formed on a cathode was investigated by TEM observation and FT-IR spectroscopy. It was found that the main product formed in discharge was not an ideal compound, Li2O2, but was carbonate species issued from the decomposition of carbonate-based electrolyte solvent.
引用
收藏
页码：403 / 405
页数：3
相关论文
共 50 条
  • [1] ETHYLENE CARBONATE-BASED ELECTROLYTES FOR RECHARGEABLE LITHIUM BATTERIES
    TOBISHIMA, S
    ARAKAWA, M
    HIRAI, T
    YAMAKI, J
    [J]. JOURNAL OF POWER SOURCES, 1989, 26 (3-4) : 449 - 454
  • [2] The Theoretical Energy Densities of Dual-Electrolytes Rechargeable Li-Air and Li-Air Flow Batteries
    Zheng, J. P.
    Andrei, P.
    Hendrickson, M.
    Plichta, E. J.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (01) : A43 - A46
  • [3] Effects of aqueous electrolytes on the voltage behaviors of rechargeable Li-air batteries
    He, Hui
    Niu, Wei
    Asl, Nina Mahootcheian
    Salim, Jason
    Chen, Rongrong
    Kim, Youngsik
    [J]. ELECTROCHIMICA ACTA, 2012, 67 : 87 - 94
  • [4] Current Collectors for Rechargeable Li-Air Batteries
    Veith, Gabriel M.
    Dudney, Nancy J.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (06) : A658 - A663
  • [5] Nanoporous Catalysts for Rechargeable Li-air Batteries
    Cheng Fangyi
    Chen Jun
    [J]. ACTA CHIMICA SINICA, 2013, 71 (04) : 473 - 477
  • [6] Hybrid Ionic Liquid Propylene Carbonate-Based Electrolytes for Aluminum-Air Batteries
    Levy, Natasha Ronith
    Lifshits, Shira
    Yohanan, Eitan
    Ein-Eli, Yair
    [J]. ACS APPLIED ENERGY MATERIALS, 2020, 3 (03): : 2585 - 2592
  • [7] Ionic Liquid Electrolytes for Li-Air Batteries: Lithium Metal Cycling
    Grande, Lorenzo
    Paillard, Elie
    Kim, Guk-Tae
    Monaco, Simone
    Passerini, Stefano
    [J]. INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2014, 15 (05): : 8122 - 8137
  • [8] Making Li-Air Batteries Rechargeable: Material Challenges
    Shao, Yuyan
    Ding, Fei
    Xiao, Jie
    Zhang, Jian
    Xu, Wu
    Park, Sehkyu
    Zhang, Ji-Guang
    Wang, Yong
    Liu, Jun
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2013, 23 (08) : 987 - 1004
  • [9] A Rechargeable Li-Air Fuel Cell Battery Based on Garnet Solid Electrolytes
    Jiyang Sun
    Ning Zhao
    Yiqiu Li
    Xiangxin Guo
    Xuefei Feng
    Xiaosong Liu
    Zhi Liu
    Guanglei Cui
    Hao Zheng
    Lin Gu
    Hong Li
    [J]. Scientific Reports, 7
  • [10] ETHYLENE CARBONATE-BASED TERNARY MIXED-SOLVENT ELECTROLYTES FOR RECHARGEABLE LITHIUM BATTERIES
    TOBISHIMA, SI
    HAYASHI, K
    SAITO, KI
    YAMAKI, JI
    [J]. ELECTROCHIMICA ACTA, 1995, 40 (05) : 537 - 544
12345