A study of third-order nonlinear optical properties for anthraquinone derivatives

被引:30
|
作者
Meng, QH [1 ]
Yan, WF [1 ]
Yu, MJ [1 ]
Huang, DY [1 ]
机构
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China
关键词
1,4-diamino-2,3-diphenoxy-anthraquinone; finite field; molecular configuration; second hyperpolarizability; degenerate four-wave mixing;
D O I
10.1016/S0143-7208(02)00123-7
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The ground-state geometry, second hyperpolarizabilities of the anthraquinone derivatives have been studied using finite field (FF) The molecular configurations and calculated gamma(zzzz) values are considerably affected by substituents. The third-order nonlinear optical property of 1,4-diamino-2,3-diphenoxy-anthraquinone has been measured using picosecond degenerate four-wave mixing. The third-order nonlinear optical susceptibility chi((3)) of the dye is as high as 1.16 x 10(-12) esu. The second hyperpolarizability (gamma) value is 5.71 X 10(-31) esu. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:145 / 149
页数:5
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