Synergistic effect on thermal behavior during co-pyrolysis of lignocellulosic biomass model components blend with bituminous coal

被引:165
|
作者
Wu, Zhiqiang [1 ]
Wang, Shuzhong [1 ]
Zhao, Jun [1 ]
Chen, Lin [1 ]
Meng, Haiyu [1 ]
机构
[1] Xi An Jiao Tong Univ, Sch Energy & Power Engn, Minist Educ, Key Lab Thermofluid Sci & Engn, Xian 710049, Shaanxi, Peoples R China
关键词
Synergistic effect; Lignocellulosic biomass; Co-pyrolysis; Kinetics; Coal; MASS SPECTROMETRIC ANALYSIS; RICE STRAW; RANK COALS; COMBUSTION; CELLULOSE; GASIFICATION;
D O I
10.1016/j.biortech.2014.06.105
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Co-thermochemical conversion of lignocellulosic biomass and coal has been investigated as an effective way to reduce the carbon footprint. Successful evaluating on thermal behavior of the co-pyrolysis is prerequisite for predicting performance and optimizing efficiency of this process. In this paper, pyrolysis and kinetics characteristics of three kinds of lignocellulosic biomass model components (cellulose, hemicellulose, and lignin) blended with a kind of Chinese bituminous coal were explored by thermogravimetric analyzer and Kissinger-Akahira-Sunose method. The results indicated that the addition of model compounds had different synergistic effects on thermal behavior of the bituminous coal. The cellulose showed positive synergistic effects on the thermal decomposition of the coal bituminous coal with lower char yield than calculated value. For hemicellulose and lignin, whether positive or negative synergistic was related to the mixed ratio and temperature range. The distribution of the average activation energy values for the mixtures showed nonadditivity performance. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:220 / 228
页数:9
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