Assembly of Tunable Supramolecular Organometallic Catalysts with Cyclodextrins

被引：18
|
作者：
Leclercq, Loic [1 ]
Schmitzer, Andreea R. [1 ]
机构：
[1] Univ Montreal, Dept Chem, Montreal, PQ H3C 3J7, Canada
来源：
ORGANOMETALLICS | 2010年 / 29卷 / 15期
基金：
加拿大自然科学与工程研究理事会; 加拿大创新基金会;
关键词：
BETA-CYCLODEXTRIN; SERINE OCTAMER; HIGHER OLEFINS; HYDROFORMYLATION; COMPLEXATION; CHEMISTRY; LIGANDS; SALTS;
D O I：
10.1021/om1006215
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Methylated-beta-CDs were used to activate a catalyst by ligand solution trapping, to form second-sphere coordination by ligand complexation, and to increase the regioselectivity of biphasic and homogeneous hydroformylation reactions. Different methylation degrees of the beta-CD allow assembly of hydrophobic or hydrophilic catalysts that can be employed in homogeneous or biphasic hydroformylation reactions.
引用
收藏
页码：3442 / 3449
页数：8
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