Assembly of Tunable Supramolecular Organometallic Catalysts with Cyclodextrins

被引：18

作者：

Leclercq, Loic ^{[1
]}

Schmitzer, Andreea R. ^{[1
]}

机构：

[1] Univ Montreal, Dept Chem, Montreal, PQ H3C 3J7, Canada

来源：

ORGANOMETALLICS | 2010年 / 29卷 / 15期

基金：

加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

BETA-CYCLODEXTRIN; SERINE OCTAMER; HIGHER OLEFINS; HYDROFORMYLATION; COMPLEXATION; CHEMISTRY; LIGANDS; SALTS;

D O I：

10.1021/om1006215

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Methylated-beta-CDs were used to activate a catalyst by ligand solution trapping, to form second-sphere coordination by ligand complexation, and to increase the regioselectivity of biphasic and homogeneous hydroformylation reactions. Different methylation degrees of the beta-CD allow assembly of hydrophobic or hydrophilic catalysts that can be employed in homogeneous or biphasic hydroformylation reactions.

引用

页码：3442 / 3449

页数：8

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