Structurally characterized trinuclear nickel(II) and copper(II) Salamo-type complexes: syntheses, Hirshfeld analyses and fluorescent properties

被引：84

作者：

Zhang, Yu ^{[1
]}

Liu, Ling-Zhi ^{[1
]}

Peng, Yun-Dong ^{[1
]}

Li, Na ^{[1
]}

Dong, Wen-Kui ^{[1
]}

机构：

[1] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Gansu, Peoples R China

来源：

TRANSITION METAL CHEMISTRY | 2019年 / 44卷 / 07期

基金：

美国国家科学基金会;

关键词：

CRYSTAL-STRUCTURES; SCHIFF-BASE; SUPRAMOLECULAR STRUCTURES; SPECTROSCOPIC PROPERTIES; NI(II) COMPLEXES; LIGAND SYNTHESES; CU(II); ZN(II);

D O I：

10.1007/s11243-019-00325-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two trinuclear Ni(II) and Cu(II) coordination compounds [{Ni(L-1)(C2H5OH)}(2)(mu-OAc)(2)Ni]center dot 2C(2)H(5)OH (1) and [{Cu(L-2) (CH3OH)}(2)(mu-OAc)(2)Cu]center dot 2CH(3)OH (2) constructed from asymmetrical Salamo-type ligands H2L1 and H2L2 (H2L1 = 5-(N,N'-diethylamino)-2,2'-[ethylenediyldioxybis(nitrilomethylidyne)]diphenol and H2L2 = 2,2'-[ethylenediyldioxybis(nitrilomethylidyne)]naphtholphenol) were synthesized and characterized by physicochemical and spectroscopic methods. Complex 1 is a centrosymmetrical trinuclear Ni(II) coordination compound. Three hexa-coordinated Ni(II) atoms have slightly distorted octahedral geometries. Complex 2 contains three hexa-coordinated Cu(II) atoms bearing distorted octahedral geometries too. In addition, the thermal analyses and Hirshfeld surfaces analyses of complexes 1 and 2 have been discussed in detail.

引用

页码：627 / 639

页数：13

共 50 条

[21] An Unprecedented Trinuclear Nickel(II) Complex Assembled from an Asymmetric Salamo-Type Ligand
Zhang, Y.
Liu, L. -Z.
Gao, L.
Akogun, S. -F.
Dong, W. -K.
JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 59 (07) : 1664 - 1673
[22] Zinc(II) and copper(II) complexes containing asymmetrical Salamo-type ligands: syntheses, crystal structures, and spectroscopic behaviors
Dong, Wen-Kui
Sun, Yin-Xia
Dong, Xiu-Yan
Xing, Si-Jia
Wang, Li
JOURNAL OF COORDINATION CHEMISTRY, 2013, 66 (18) : 3291 - 3304
[23] An Unprecedented Trinuclear Nickel(II) Complex Assembled from an Asymmetric Salamo-Type Ligand
Y. Zhang
L.-Z. Liu
L. Gao
S.-F. Akogun
W.-K. Dong
Journal of Structural Chemistry, 2018, 59 : 1664 - 1673
[24] Three new Salamo-type homotrinuclear nickel(II) complexes possessing solvent effects: Syntheses, structures and fluorescence properties
Pu, Lu-Mei
Long, Hai-Tao
Zhang, Yang
Bai, Yang
Dong, Wen-Kui
POLYHEDRON, 2017, 128 : 57 - 67
[25] Structural, spectroscopic, fluorescent, and computational studies of binuclear copper (II) and zinc (II) complexes with an asymmetric salamo-type ligand
Chai, Zhi-Lei
Zhang, Hai-Wei
Wang, Li
Dong, Wen-Kui
APPLIED ORGANOMETALLIC CHEMISTRY, 2024, 38 (11)
[26] Novel structurally characterized hetero-bimetallic [Zn(II)2M(II)] (M = Ca and Sr) bis(salamo)-type complexes: DFT calculation, Hirshfeld analyses, antimicrobial and fluorescent properties
Liu, Chang
An, Xiao-Xin
Cui, Yong-Fan
Xie, Ke-Feng
Dong, Wen-Kui
APPLIED ORGANOMETALLIC CHEMISTRY, 2020, 34 (01)
[27] Novel multinuclear transition metal(II) complexes based on an asymmetric Salamo-type ligand: Syntheses, structure characterizations and fluorescent properties
Dong, Wen-Kui
Zhang, Jing
Zhang, Yang
Li, Na
INORGANICA CHIMICA ACTA, 2016, 444 : 95 - 102
[28] A Supramolecular Trinuclear Nickel(II) Complex with Asymmetric Salamo-type Ligand: Synthesis and Crystal Structure
Dong, W. -K.
Meng, J. -L.
Zhang, X. -Y.
Zhao, M. -M.
Li, G.
Dong, X. -Y.
ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (17) : 9970 - 9974
[29] Trinuclear Co(II) and Mononuclear Ni(II) Salamo-Type Bisoxime Coordination Compounds
Li, Xiao-Yan
Kang, Quan-Peng
Liu, Ling-Zhi
Ma, Jian-Chun
Dong, Wen-Kui
CRYSTALS, 2018, 8 (01):
[30] Syntheses, Structures, Hirshfeld Analyses and Fluorescent Properties of Two NM and Zn(II) Complexes Constructed From a Bis(salamo)-like Ligand
Liu Ling-Zhi
Yu Meng
Li Xiao-Yan
Kang Quan-Peng
Dong Wen-Kui
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2019, 35 (07) : 1283 - 1294

← 1 2 3 4 5 →