Transition-metal-doped Fe2O3 nanoparticles for oxygen evolution reaction

被引：47
|
作者：
Yin, Yichun [1 ]
Zhang, Xiwang [2 ]
Sun, Chenghua [3 ]
机构：
[1] Monash Univ, Sch Chem, ARC Ctr Excellence Electromat Sci, Wellington Rd, Clayton, Vic 3800, Australia
[2] Monash Univ, Dept Chem Engn, Wellington Rd, Clayton, Vic 3800, Australia
[3] Swinbume Univ Technol, Fac Sci Engn & Technol, John St, Hawthorn, Vic 3122, Australia
来源：
PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL | 2018年 / 28卷 / 04期
基金：
澳大利亚研究理事会;
关键词：
Hematite; Metal doping; Water splitting; Oxygen evolution reaction; PHOTO-FENTON REACTION; WATER OXIDATION; PHOTOELECTROCHEMICAL PROPERTIES; SEMICONDUCTOR ELECTRODES; EFFECTIVE DOPANTS; ALPHA-FE2O3; HEMATITE; PERFORMANCE; FILMS; TRANSPARENT;
D O I：
10.1016/j.pnsc.2018.07.005
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Hematite (alpha-Fe2O3) has been extensively studied as a promising photocatalyst, with the capacity to split water under visible light. To tune its electronic structure and improve the performance for oxygen evolution reaction (OER), high-quality single crystals of alpha-Fe2O3 nanoparticles were synthesized and doped by various transition metals (M = V, Cr, Mn, Zn, Co, Ni, Cu, Nb, Mo, Ti) by a molten-salt flux method. Optical, electronic and catalytic properties of transition-metal-doped alpha-Fe2O3 (TM-doped alpha-Fe2O3) have been systematically investigated. Cobalt has been identified as the best dopant for alpha-Fe2O3, reducing the OER overpotential by 0.16 V with respect to the undoped.
引用
收藏
页码：430 / 436
页数：7
相关论文
共 50 条
  • [21] Evolution of the Fe3+ Ion Local Environment During the Phase Transition ε-Fe2O3 → α-Fe2O3
    S. S. Yakushkin
    D. A. Balaev
    A. A. Dubrovskiy
    S. V. Semenov
    K. A. Shaikhutdinov
    M. A. Kazakova
    G. A. Bukhtiyarova
    O. N. Martyanov
    O. A. Bayukov
    Journal of Superconductivity and Novel Magnetism, 2018, 31 : 1209 - 1217
  • [22] Facile Synthesis of 3d Transition-Metal-Doped α-Co(OH)2 Nanomaterials in Water-Methanol Mediated with Ammonia for Oxygen Evolution Reaction
    Cao, Bo
    Luo, Chunhua
    Lao, Jie
    Chen, Hanging
    Qi, Ruijuan
    Lin, Hechun
    Peng, Hui
    ACS OMEGA, 2019, 4 (15): : 16612 - 16618
  • [23] Confinement of Fe2O3 nanoparticles in the shell of N-doped carbon hollow microsphere for efficient oxygen reduction reaction
    Xiao, Zhourong
    Hou, Fang
    Li, Yueting
    Zhang, Rongrong
    Shen, Guoqiang
    Wang, Li
    Zhang, Xiangwen
    Wang, Qingfa
    Li, Guozhu
    CHEMICAL ENGINEERING SCIENCE, 2019, 207 : 235 - 246
  • [24] Observation of ε - Fe2O3 nanoparticles precipitated in potassium aluminoborate glasses doped with 4 mol % Fe2O3
    Eremina, R. M.
    Yatsyk, I., V
    Shestakov, A., V
    Fazlizhanov, I. I.
    Gavrilova, T. P.
    Milovich, F. O.
    Zinnatullin, A. L.
    Vagizov, F. G.
    Gilmutdinov, I. F.
    Shirshnev, P. S.
    Sobolev, D., I
    Nikonorov, N., V
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2019, 133 : 7 - 14
  • [25] Enhanced Performance of Alkali Metal Doped Fe2O3 and Fe2O3/Al2O3 Composites As Oxygen Carrier Material in Chemical Looping Combustion
    Liu, Lu
    Zachariah, Michael R.
    ENERGY & FUELS, 2013, 27 (08) : 4977 - 4983
  • [26] Synthesis of Fe2O3 nanoparticles in different reaction media
    Chaianansutcharit, Soamwadee
    Mekasuwandumrong, Okorn
    Praserthdam, Piyasan
    CERAMICS INTERNATIONAL, 2007, 33 (04) : 697 - 699
  • [27] Transition-Metal-Doped α-MnO2 Nanorods as Bifunctional Catalysts for Efficient Oxygen Reduction and Evolution Reactions
    Lubke, Mechthild
    Sumboja, Afriyanti
    McCafferty, Liam
    Armer, Ceilidh F.
    Handoko, Albertus D.
    Du, Yonghua
    McColl, Kit
    Cora, Furio
    Brett, Dan
    Liu, Zhaolin
    Darr, Jawwad A.
    CHEMISTRYSELECT, 2018, 3 (09): : 2613 - 2622
  • [28] Synthesis and physical characterization of γ-Fe2O3 and (α+γ)-Fe2O3 nanoparticles
    P. Bhavani
    N. Ramamanohar Reddy
    I. Venkata Subba Reddy
    Journal of the Korean Physical Society, 2017, 70 : 150 - 154
  • [29] Fe2O3 hollow nanorods/CNT composites as an efficient electrocatalyst for oxygen evolution reaction
    Bandal, H. A.
    Jadhav, A. R.
    Chaugule, A. A.
    Chung, W-J.
    Kim, H.
    ELECTROCHIMICA ACTA, 2016, 222 : 1316 - 1325
  • [30] Facile synthesis of Er-MOF/Fe2O3 nanocomposite for oxygen evolution reaction
    Shabbir, Bushra
    Ansari, Mohd Zahid
    Manzoor, Sumaira
    Abid, Abdul Ghafoor
    Nisa, Mehar Un
    Shawky, Ahmed M.
    Znaidia, Sami
    Aman, Salma
    Ashiq, Muhammad Naeem
    Taha, T. A.
    MATERIALS CHEMISTRY AND PHYSICS, 2022, 292
12345