Structure optimization of Prussian blue analogue cathode materials for advanced sodium ion batteries

被引：225
|
作者：
Yang, Dezhi [1 ]
Xu, Jing [1 ]
Liao, Xiao-Zhen [1 ]
He, Yu-Shi [1 ]
Liu, Haimei [2 ]
Ma, Zi-Feng [1 ]
机构：
[1] Shanghai Jiao Tong Univ, Dept Chem Engn, Inst Electrochem & Energy Technol, Shanghai 200240, Peoples R China
[2] Shanghai Univ Elect Power, Coll Environm & Chem Engn, Shanghai 200090, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 87期
关键词：
ENERGY-STORAGE; LOW-COST; CHALLENGES; ELECTRODE; CHEMISTRY;
D O I：
10.1039/c4cc05830e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A structure optimized Prussian blue analogue Na1.76Ni0.12Mn0.88-[Fe(CN)(6)](0.98) (PBMN) is synthesized and investigated. Coexistence of inactive Ni2+(Fe-C N-Ni group) with active Mn2+/(3+) (Fe-C N-Mn group) balances the structural disturbances caused by the redox reactions. This cathode material exhibits particularly excellent cycle life with high capacity (118.2 mA h g(-1)).
引用
收藏
页码：13377 / 13380
页数：4
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