Laser-induced, one-step synthesis of cyclodextrin carboxylic acids and their esters

被引：0
|
作者：
Jankowski, Christopher K. [1 ,2 ]
Pelletier, Andre [1 ]
Aychet, Nicolas [2 ]
Hocquelet, Celine [2 ]
Lacour, Jean-Luc [2 ]
Bresson, Carole [2 ]
机构：
[1] Univ Moncton, Dept Chim & Biochim, Moncton, NB E1A 3E9, Canada
[2] CEA Saclay, F-91191 Gif Sur Yvette, France
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY | 2014年 / 53卷 / 12期
关键词：
Cyclodextrin; laser-assisted; solvolysis; NMR; mechanism; PRODUCTS;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
alpha- and beta-Cyclodextrin 6-azides (or 6A,6D-diazide) when subjected to laser irradiation followed by mild hydrolysis, lead, via the aldehyde, to small yields of corresponding acids, or in presence of alcohol to methyl or ethyl esters. The structures of compounds obtained have been identified using ESI mass and NMR spectroscopy.
引用
收藏
页码：1611 / 1614
页数：4
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