A Simple and Environmentally Benign Method for Sulfoxidation of Sulfides with Hydrogen Peroxide

被引：28
|
作者：
Liu, Fenglan
Fu, Zaihui [1 ]
Liu, Yachun
Lu, Chunli
Wu, Youyu
Xie, Fang
Ye, Zhengpei
Zhou, Xiaoping
Yin, Dulin
机构：
[1] Hunan Normal Univ, Coll Chem & Chem Engn, Minist Educ China, Key Lab Resource Fine Proc & Adv Mat Hunan Prov, Changsha 410081, Hunan, Peoples R China
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2010年 / 49卷 / 05期
基金：
中国国家自然科学基金;
关键词：
TERT-BUTYL HYDROPEROXIDE; SELECTIVE OXIDATION; CATALYTIC-OXIDATION; MECHANISM; H2O2; IRON; EFFICIENT; COMPLEX; ACID;
D O I：
10.1021/ie9017572
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
The development of a simple, efficient, and environmentally benign method for the sulfoxidation Of Sulfides with aqueous hydrogen peroxide is of importance for the large-scale industrial production of sulfoxides. This article first discloses that various aryl and alkyl Sulfides, Without help of any catalyst and extra solvent, call be directly oxidized by 30% aqueous hydrogen peroxide to the corresponding sulfoxides with good to excellent yield at 60 degrees C. Furthermore, the present Method has Outstanding advantages, with regard to reaction rate and sulfoxide yield, compared with a series of organic solvents-mediated reactions.
引用
收藏
页码：2533 / 2536
页数：4
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