Capillary electrophoretic determination of tetramethylthuram disulphide (Thiram)

被引:21
|
作者
Malik, AK [1 ]
Faubel, W [1 ]
机构
[1] Forschungszentrum Karlsruhe GmbH, Inst Instrumentalle Analyt, D-76021 Karlsruhe, Germany
关键词
Thiram; capillary electrophoresis; environmental samples; Nabam; wheat samples;
D O I
10.1080/00032710008543174
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A simple and sensitive capillary electrophoretic method was developed for the separation and determination of Thiram in boric acid buffer by direct UV absorbance detection at lambda = 254 nm. The separation behaviour of Thiram from Nabam was studied and it is dependent on pH and the nature of the buffer. The detection limit (S/N = 3) is 0.5 mu g/ml for Thiram, The method was successfully applied to the analysis of wheat samples spiked with Thiram.
引用
收藏
页码:2055 / 2064
页数:10
相关论文
共 50 条
  • [31] Capillary electrophoretic determination of citalopram in pharmaceutical tablets and serum
    Satana, E.
    Uysal, U. Dilek
    Goger, N. G.
    Tuncel, M.
    CHROMATOGRAPHIA, 2006, 64 (5-6) : 317 - 320
  • [32] Capillary electrophoretic determination of thiosulfate and its oxidation products
    Padarauskas, A
    Paliulionyte, V
    Ragauskas, R
    Dikcius, A
    JOURNAL OF CHROMATOGRAPHY A, 2000, 879 (02) : 235 - 243
  • [33] Capillary electrophoretic enantioselective determination of zopiclone and its impurities
    Tonon, Milena Araujo
    Bonato, Pierina Sueli
    ELECTROPHORESIS, 2012, 33 (11) : 1606 - 1612
  • [34] DETERMINATION OF THE ELECTROPHORETIC MOBILITY OF POLYSTYRENE PARTICLES BY CAPILLARY ELECTROPHORESIS
    HUFF, BV
    MCINTIRE, GL
    JOURNAL OF MICROCOLUMN SEPARATIONS, 1994, 6 (06) : 591 - 594
  • [35] DETERMINATION OF THIRAM IN FERBAM
    LOWEN, WK
    JOURNAL OF THE ASSOCIATION OF OFFICIAL AGRICULTURAL CHEMISTS, 1961, 44 (03): : 584 - +
  • [36] Capillary electrophoretic determination of thiosulfate, sulfide and sulfite using in-capillary derivatization with iodine
    Daunoravicius, Z
    Padarauskas, A
    ELECTROPHORESIS, 2002, 23 (15) : 2439 - 2444
  • [37] Determination of estrodiol by capillary electrophoretic immunoassay with thermally reversible hydrogel
    Su, P
    Wang, YC
    Zhang, XX
    Sun, L
    Chang, WB
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2000, 21 (06): : 870 - 872
  • [38] Determination of minute enzymatic activities by means of capillary electrophoretic techniques
    Bao, JJ
    Fujima, JM
    Danielson, ND
    JOURNAL OF CHROMATOGRAPHY B, 1997, 699 (1-2): : 481 - 497
  • [39] Capillary zone electrophoretic separation and determination of imidazolic antifungal drugs
    Arranz, A
    Echevarría, C
    Moreda, JM
    Cid, A
    Arranz, JF
    JOURNAL OF CHROMATOGRAPHY A, 2000, 871 (1-2) : 399 - 402
  • [40] Development and validation of a capillary electrophoretic method for the determination of amiodarone and desethylamiodarone
    T. Pérez-Ruiz
    C. Martínez-Lozano
    A. Sanz
    E. Bravo
    Chromatographia, 2002, 56 : 63 - 67