Cooperative Catalysis with Iron and a Chiral Bronsted Acid for Asymmetric Reductive Amination of Ketones

被引：76

作者：

Zhou, Shaolin ^{[1
,2
]}

Fleischer, Steffen ^{[1
]}

Jiao, Haijun ^{[1
]}

Junge, Kathrin ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

[2] Cent China Normal Univ, CCNU OttawaU Joint Res Ctr, State Key Lab Pesticide & Chem Biol, Minist Educ,Coll Chem, Wuhan 430079, Hubei, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2014年 / 356卷 / 16期

基金：

美国国家科学基金会;

关键词：

amines; Bronsted acids; catalysis; iron; reductive amination; ENANTIOSELECTIVE HYDROGENATION; TRANSITION-METAL; ALKYLATION; ALDEHYDES;

D O I：

10.1002/adsc.201400328

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The direct asymmetric reductive amination (DARA) of ketones with anilines is described by combining a chiral Bronsted acid (TRIP) and the non-chiral Knolker iron complex as the catalyst system. In situ-formed imines are reduced with molecular hydrogen to give chiral amines in high yields (90%) and enantioselectivities of up to 99% ee.

引用

页码：3451 / 3455

页数：5

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