Activity Coefficients of Potassium Chloride in Ethylene Glycol-Water Mixtures Using Electromotive Force Measurements at (278.15, 288.15, 298.15, and 308.15) K

被引：15

作者：

Ma, Yanyan ^{[1
]}

Li, Shu'ni ^{[1
]}

Zhai, Quanguo ^{[1
]}

Jiang, Yucheng ^{[1
]}

Hu, Mancheng ^{[1
]}

机构：

[1] Shaanxi Normal Univ, Sch Chem & Mat Sci, Key Lab Macromol Sci Shaanxi Prov, Xian 710062, Shaanxi, Peoples R China

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2010年 / 55卷 / 04期

关键词：

EPSILON-INCREASING COSOLVENT; AQUEOUS MIXTURES; METHANOL-WATER; THERMODYNAMIC PROPERTIES; ELEVATED-TEMPERATURES; RELATIVE PERMITTIVITY; ELECTROLYTE-SOLUTIONS; SOLVENT MIXTURES; ETHANOL MIXTURES; EMF-MEASUREMENTS;

D O I：

10.1021/je900690d

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The Mean activity coefficients of KCl were determined in ethylene glycol-water mixed solvents, in the range of (10. 20, 30, and 40) % ethylene glycol, from the electromotive. force (EM F) data at (278.15, 288 15, 298.15. and 308 15) K The Pitzer and extended Debye-Huckel equations were used to describe the nonideal behavior of the electrolyte. and the corresponding activity and osmotic coefficients were determined Moreover. the standard Gibbs energy of transference of KCl-ethylene glycol-water was evaluated.

引用

页码：1573 / 1579

页数：7

共 50 条

[21] THERMODYNAMICS OF HYDROCHLORIC-ACID IN ETHYLENE-GLYCOL + WATER MIXTURES FROM ELECTROMOTIVE-FORCE MEASUREMENTS
ELSEMONGY, MM
KENAWY, IM
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-WIESBADEN, 1982, 129 (02): : 185 - 196
[22] Excess molar volumes and viscosities of the binary mixtures of ethylene glycol monoisopropyl ether with water at 298.15, 308.15 and 318.15K
Pal, A
Singh, YP
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1997, 36 (05): : 421 - 424
[23] Activity Coefficients of RbCl in Ethylene Glycol plus Water and Glycerol plus Water Mixed Solvents at 298.15 K
Tang, Jing
Ma, Yanyan
Li, Shu'ni
Zhai, Quanguo
Jiang, Yucheng
Hu, Mancheng
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2011, 56 (05): : 2356 - 2361
[24] OSMOTIC AND ACTIVITY-COEFFICIENTS FOR MIXTURES OF LITHIUM CHLORIDE WITH BARIUM CHLORIDE AND CESIUM CHLORIDE WITH BARIUM CHLORIDE IN WATER AT 298.15 K
LINDENBAUM, S
RUSH, RM
ROBINSON, RA
JOURNAL OF CHEMICAL THERMODYNAMICS, 1972, 4 (03): : 381 - +
[25] Activity Coefficients of RbF or CsF in the Ethene Glycol plus Water System by Protentiometric Measurements at 298.15 K
Wang, Lei
Li, Shu'ni
Zhai, Quanguo
Jiang, Yucheng
Hu, Mancheng
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2011, 56 (12): : 4416 - 4421
[26] The activity coefficients of thallous chloride in ethylene glycol-water solutions determined by e m f and solubility data at 25 degrees
Black, OD
Garrett, AB
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1943, 65 : 862 - 865
[27] Thermodynamic study of potassium chloride in glycerol-water mixed solvents using electromotive force measurements at (298.2, 303.2 and 310.2) K
Bakhtiari, Maryam
Ghalami-Choobar, Bahram
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2015, 754 : 109 - 117
[28] Activity Coefficients of NaCl in Aqueous Mixtures with High Relative Permittivity Cosolvent: Ethylene Carbonate + Water at 298.15 K
Hernandez-Luis, Felipe
Rodriguez-Raposo, Raquel
Galleguillos, Hector R.
Morales, Jaime W.
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2010, 55 (09): : 3349 - 3355
[29] Activity coefficients of NaF in aqueous mixtures with ε-increasing co-solvent:: ethylene carbonate-water mixtures at 298.15 K
Hernández-Luis, F
Vazquez, MV
Esteso, MA
FLUID PHASE EQUILIBRIA, 2004, 218 (02) : 295 - 304
[30] Electrical Conductances of Tetrabutylammonium Bromide, Sodium Tetraphenylborate, and Sodium Bromide in Ethylene Glycol (1) + Water (2) Mixtures at (298.15, 303.15, 308.15, and 318.15) K
Sharma, Ramesh
Das, Chanchal
Chatterjee, Amritendu
Das, Bijan
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2009, 54 (06): : 1899 - 1904

← 1 2 3 4 5 →