Pyridino[3,4]tribenzoporphyrazines: edge-to-face versus face-to-face assemblies among phthalocyanine analogues

被引：47

作者：

Cook, MJ

JafariFini, A

机构：

[1] School of Chemical Sciences, University of East Anglia, Norwich

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1997年 / 7卷 / 12期

关键词：

D O I：

10.1039/a706818b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The metal-free and nickel derivatives of hexaoctylpyridino [3,4] tribenzoporphyrazine generate conventional face-to-face aggregates in solution, exhibit columnar mesophases and form columnar assemblies upon evaporation of solutions. By contrast, the zinc derivative forms alternative edge-to-face complexes through axial ligation of one molecule to the zinc atom of another, a process which inhibits mesophase behaviour and leads to new types of visible region absorption signatures.

引用

页码：2327 / 2329

页数：3

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