Formation of WO3 from various precursors

被引：2
|
作者：
Plyasova, L. M. [1 ]
Molina, I. Yu. [1 ]
Kustova, G. N. [1 ]
Litvak, G. S. [1 ]
Nizovskii, A. I. [1 ]
Gavrilov, A. N. [2 ]
机构：
[1] Boreskov Inst Catalysis SB RAS, Novosibirsk 630090, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
来源：
JOURNAL OF SURFACE INVESTIGATION | 2009年 / 3卷 / 06期
基金：
俄罗斯基础研究基金会;
关键词：
FILMS; PARATUNGSTATE; BEHAVIOR;
D O I：
10.1134/S1027451009060044
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
A comparative study of tungsten oxide formation from various precursors has been carried out using a complex of physicochemical methods. Crystallization of WO3 has been shown to pass through metastable states in all cases. For electrodeposited oxotungstate films, the structure of tungsten oxides depends on electrodeposition conditions and adsorption properties of substrate metal with respect to hydrogen; at temperatures below 600 A degrees C the stoichiometric composition of WO3 is not attained.
引用
收藏
页码：869 / 875
页数：7
相关论文
共 50 条
  • [41] Formation of monodisperse (WO3)3 clusters on TiO2(110)
    Bondarchuk, Oleksandr
    Huang, Xin
    Kim, Jooho
    Kay, Bruce D.
    Wang, Lai-Sheng
    White, J. M.
    Dohnalek, Zdenek
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (29) : 4786 - 4789
  • [42] Electrochemical lithium intercalation into WO3 and lithium tungstates Lix WO3+x /2 of various structures
    Aishui Yu
    Naoaki Kumagai
    Zhaolin Liu
    Jim Y. Lee
    Journal of Solid State Electrochemistry, 1998, 2 : 394 - 400
  • [43] Vibrational spectra of WO3•nH2O and WO3 polymorphs
    Kustova, G. N.
    Chesalov, Yu. A.
    Plyasova, L. M.
    Molina, I. Yu.
    Nizovskii, A. I.
    VIBRATIONAL SPECTROSCOPY, 2011, 55 (02) : 235 - 240
  • [44] Transparent WO3/Ag/WO3 electrode for flexible organic solar cells
    Wang, Yishan
    He, Bo
    Wang, Haowei
    Xu, Junfeng
    Ta, Tage
    Li, Weile
    Wang, Qi
    Yang, Shengyi
    Tang, Yi
    Zou, Bingsuo
    MATERIALS LETTERS, 2017, 188 : 107 - 110
  • [45] MECHANISM OF CAWO4 FORMATION IN SOLID-STATE FROM CAO AND WO3
    FLOR, G
    MASSAROTTI, V
    RICCARDI, R
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1977, 32 (02): : 160 - 162
  • [46] INSITU PHOTOEMISSION FROM SEMICONDUCTING WO3 ELECTRODES
    BUTLER, MA
    SURFACE SCIENCE, 1980, 101 (1-3) : 155 - 161
  • [47] Reactivity of hydrogen and methanol on (0 0 1) surfaces of WO3, ReO3, WO3/ReO3 and ReO3/WO3
    Ling, Sanliang
    Mei, Donghai
    Gutowski, Maciej
    CATALYSIS TODAY, 2011, 165 (01) : 41 - 48
  • [48] BACKSCATTERING OF H AND HE FROM W AND WO3
    BHATTACHARYA, RS
    ECKSTEIN, W
    VERBEEK, H
    JOURNAL OF NUCLEAR MATERIALS, 1979, 79 (02) : 420 - 422
  • [49] Formation of new tungsten bronzes:: electrochemical zinc insertion in WO3
    Martinez-de la Cruz, A
    Torres-Martinez, LM
    Garcia-Alvarado, F
    Moran, E
    Alario-Franco, MA
    JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (08) : 1805 - 1807
  • [50] THERMOCONDENSATION OF WO3 FROM TUNGSTATOSILICIC ACID HYDRATES
    HEGEDUS, AJ
    GADO, P
    SCHLOSSE.G
    NEUGEBAU.J
    ACTA CHIMICA ACADEMIAE SCIENTARIUM HUNGARICAE, 1970, 66 (04): : 349 - &
12345