Adsorption and separation behaviors of molybdenum from high-level liquid waste using a silica-based hydroxyoxime impregnated adsorbent

被引：6

作者：

Ito, Tatsuya ^{[1
]}

Kim, Seong-Yun ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Engn, Dept Quantum Sci & Energy Engn, Aoba Ku, 6-6-01-2 Aza Aoba Aramaki, Sendai, Miyagi 9808579, Japan

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2018年 / 316卷 / 03期

关键词：

Macroporous silica-based adsorbent; Hydroxyoxime; Molybdenum; Adsorption; High-level liquid waste; COORDINATION CHEMISTRY; EXTRACTANT MIXTURES; LIX; 63; CHROMATOGRAPHY; PALLADIUM(II);

D O I：

10.1007/s10967-018-5838-9

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

To separate Mo(VI) from high-level liquid waste, a silica-based (anti-DEHDO + Dodec)/SiO2-P adsorbent was synthesized by impregnating an anti-isomer of 5,8-dietyl-7-hydroxy-6-dodecanonoxime (DEHDO) as a hydroxyoxime-type extractant and a molecule modifier of 1-dodecanol into a SiO2-P support, where "P" indicates the polymerized styrene-divinylbenzene inside macroporous SiO2 particles. Adsorption and separation behaviors of Mo(VI) in HNO3 solutions onto the adsorbent were investigated by batch and column methods, respectively. The adsorbent can effectively adsorb Mo(VI) in both methods. In addition, Pd(II) and Zr(IV) contained in the simulated high-level liquid waste were successfully isolated by the adsorbent packed column, respectively.

引用

页码：1165 / 1172

页数：8

共 50 条

[31] A novel partitioning process for treatment of high level liquid waste using macroporous silica-based adsorbents
S.-Y. Kim
Y. Xu
T. Ito
Y. Wu
T. Tada
K. Hitomi
E. Kuraoka
K. Ishii
Journal of Radioanalytical and Nuclear Chemistry, 2013, 295 : 1043 - 1050
[32] Separation of Fission Products in High-Level Liquid Waste
Ohashi, Akira
ANALYTICAL SCIENCES, 2021, 37 (10) : 1319 - 1320
[33] Separation of Fission Products in High-Level Liquid Waste
Akira Ohashi
Analytical Sciences, 2021, 37 : 1319 - 1320
[34] Adsorption Behaviors of Palladium Ion from Nitric Acid Solution by a Silica-based Hybrid Donor Adsorbent
Hao Wu
Naoki Oosawa
Masahiko Kubota
Seong-Yun Kim
Analytical Sciences, 2020, 36 : 1541 - 1545
[35] Adsorption Behaviors of Palladium Ion from Nitric Acid Solution by a Silica-based Hybrid Donor Adsorbent
Wu, Hao
Oosawa, Naoki
Kubota, Masahiko
Kim, Seong-Yun
ANALYTICAL SCIENCES, 2020, 36 (12) : 1541 - 1546
[36] Adsorption Behaviors of Platinum Group Metals in Simulated High Level Liquid Waste Using Macroporous (MOTDGA-TOA)/SiO2-P Silica-based Absorbent
Ito, Tatsuya
Kim, Seong-Yun
Xu, Yuanlai
Hitomi, Keitaro
Ishii, Keizo
Nagaishi, Ryuji
Kimura, Takaumi
SEPARATION SCIENCE AND TECHNOLOGY, 2013, 48 (17) : 2616 - 2625
[37] Removal of zirconium from high-level liquid waste by silica gel absorption
Liu, Xue-Gang
Liang, Jun-Fu
Xu, Jing-Ming
Fan, Xiao-Qiang
Yuanzineng Kexue Jishu/Atomic Energy Science and Technology, 2007, 41 (01): : 46 - 51
[38] Evaluation study on properties of a macroporous silica-based CMPO extraction resin to be used forminor actinides separation from high level liquid waste
Daisuke Tozawa
Shigekazu Usuda
Hiromichi Yamazaki
Keizo Ishii
Yuichi Sano
Yoshikazu Koma
Nuclear Science and Techniques, 2011, 22 (01) : 18 - 24
[39] Evaluation study on properties of a macroporous silica-based CMPO extraction resin to be used for minor actinides separation from high level liquid waste
Liu Ruiqin
Wei Yuezhou
Tozawa, Daisuke
Xu Yuanlai
Usuda, Shigekazu
Yamazaki, Hiromichi
Ishii, Keizo
Sano, Yuichi
Koma, Yoshikazu
NUCLEAR SCIENCE AND TECHNIQUES, 2011, 22 (01) : 18 - 24
[40] Adsorption properties and behavior of the platinum group metals onto a silica-based (Crea + TOA)/SiO2–P adsorbent from simulated high level liquid waste of PUREX reprocessing
Yuanlai Xu
Seong-Yun Kim
Tatsuya Ito
Tsutomu Tada
Keitaro Hitomi
Keizo Ishii
Journal of Radioanalytical and Nuclear Chemistry, 2013, 297 : 41 - 48

← 1 2 3 4 5 →