Double molybdate Tl2Mg4(MoO4)3:: Synthesis, structure, and properties

被引：5
|
作者：
Bazarov, B. G.
Klevtsova, R. F.
Bazarova, Ts. T.
Arkhincheeva, S. I.
Glinskaya, L. A.
Fedorov, K. N.
Bazarova, Zh. G.
机构：
[1] Russian Acad Sci, Baikal Inst Nat Management, Siberian Div, Ulan Ude 670047, Buryat Republic, Russia
[2] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 51卷 / 10期
基金：
俄罗斯基础研究基金会;
关键词：
Langbeinite; Double Molybdate; Thallium Atom; Equivalent Isotropic Thermal Parameter; Mixed Framework;
D O I：
10.1134/S0036023606100111
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Single crystals of molybdate Tl2Mg2(MoO4)(3) are grown, and its crystal structure is refined in an X-ray diffraction experiment (an automated diffractometer, MoK alpha radiation, 914 F(hkl) reflections, R = 0.0459). The crystal are cubic with a = b = c = 10.700(1)angstrom, V = 1225.0(2) angstrom(3), Z = 4, space group P2(1)3. The mixed 3D framework of the structure is built of MoO4 tetrahedra and two types of corner-sharing MgO6 octahedra. Two types of thallium atoms occupy large interstices.
引用
收藏
页码：1577 / 1580
页数：4
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