Achieving low temperature formaldehyde oxidation: A case study of NaBH4 reduced cobalt oxide nanowires

被引:23
|
作者
Chen, Yuxin [1 ]
Guo, Yuhang [3 ]
Hu, Hanxi [2 ]
Wang, Shuxian [2 ]
Lin, Ying [2 ]
Huang, Yongchao [2 ]
机构
[1] Sun Yat Sen Univ, Instrumental Anal & Res Ctr, Guangzhou 510275, Guangdong, Peoples R China
[2] Sun Yat Sen Univ, Chem Ind Res Inst, Sch Chem, Key Lab Low Carbon Chem & Energy Conservat Guangd, Guangzhou 510275, Guangdong, Peoples R China
[3] 1 Middle Sch Foshan, Foshan 528000, Peoples R China
关键词
Co3O4; Oxygen vacancy; HCHO removal; Reactive oxygen species; NaBH4; reduction; CATALYTIC-OXIDATION; CO; DEGRADATION; NANOSHEETS; DEFECTS;
D O I
10.1016/j.inoche.2017.05.005
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Oxygen vacancies enable the formation of reactive oxygen species (O-2 center dot(-)), which can react with the HCHO absorbed at the catalysts surfaces. As a result, the Co3O4 nanowires with surface oxygen vacancies demonstrated superior catalytic performance for HCHO oxidation and exhibited excellent stability in long-term test. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:20 / 23
页数:4
相关论文
共 50 条
  • [1] Nickel nanowires decorated with ultra-low palladium loading as an effective electrocatalyst for NaBH4 oxidation
    Ye, Ke
    Ma, Xiaokun
    Cang, Ruibai
    Wang, Gang
    Cheng, Kui
    Wang, Guiling
    Cao, Dianxue
    [J]. CATALYSIS SCIENCE & TECHNOLOGY, 2017, 7 (10) : 1991 - 1995
  • [2] NaBH4 reduced Mn-doped cobalt tetroxide R-MnxCo3-xO4 catalysts with plentiful oxygen vacancies for HCHO oxidation at low temperature
    Yan, Gang
    Du, Xiaojun
    Guo, Xiangwei
    Cao, Xuzheng
    Shi, Hongfei
    [J]. NEW JOURNAL OF CHEMISTRY, 2024, 48 (18) : 8314 - 8323
  • [3] Solution combustion synthesized cobalt oxide catalyst precursor for NaBH4 hydrolysis
    Groven, L. J.
    Pfeil, T. L.
    Pourpoint, T. L.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (15) : 6377 - 6380
  • [4] Atomic layer deposited cobalt oxide: An efficient catalyst for NaBH4 hydrolysis
    Nandi, Dip K.
    Manna, Joydev
    Dhara, Arpan
    Sharma, Pratibha
    Sarkar, Shaibal K.
    [J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2016, 34 (01):
  • [5] Low-temperature phase transformation in NaBH4 under pressure
    Sundqvist, B
    Andersson, O
    [J]. PHYSICAL REVIEW B, 2006, 73 (09)
  • [6] Preparation of catalysts for the Fischer–Tropsch synthesis by the deposition of cobalt reduced with NaBH4 onto a support
    O. L. Eliseev
    M. A. Kamorin
    P. E. Davydov
    A. S. Volkov
    A. V. Kazakov
    A. L. Lapidus
    [J]. Kinetics and Catalysis, 2015, 56 : 625 - 630
  • [7] NaBH4 In-situ Reduced Cobalt Catalyst Supported on Zeolite A for 1-Hexene Hydroformylation
    Fang, Yuan
    Guo, Lisheng
    Cui, Yu
    Zhang, Peipei
    Yoneyama, Yoshiharu
    Yang, Guohui
    Tsubaki, Noritatsu
    [J]. CHEMISTRYSELECT, 2019, 4 (35): : 10447 - 10451
  • [8] Preparation of catalysts for the Fischer-Tropsch synthesis by the deposition of cobalt reduced with NaBH4 onto a support
    Eliseev, O. L.
    Kamorin, M. A.
    Davydov, P. E.
    Volkov, A. S.
    Kazakov, A. V.
    Lapidus, A. L.
    [J]. KINETICS AND CATALYSIS, 2015, 56 (05) : 625 - 630
  • [9] A multifactor study of catalyzed hydrolysis of solid NaBH4 on cobalt nanoparticles: Thermodynamics and kinetics
    Andrieux, Jerome
    Swierczynski, Dariusz
    Laversenne, Laetitia
    Garron, Anthony
    Bennici, Simona
    Goutaudier, Christelle
    Miele, Philippe
    Auroux, Aline
    Bonnetot, Bernard
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (02) : 938 - 951
  • [10] Towards optimizing cobalt based metal oxide nanocrystals for hydrogen generation via NaBH4 hydrolysis
    Kim, Changwoo
    Lee, Seung Soo
    Li, Wenlu
    Fortner, John D.
    [J]. APPLIED CATALYSIS A-GENERAL, 2020, 589