Preparation of catalysts for the Fischer–Tropsch synthesis by the deposition of cobalt reduced with NaBH4 onto a support

被引：0
|
作者：
O. L. Eliseev
M. A. Kamorin
P. E. Davydov
A. S. Volkov
A. V. Kazakov
A. L. Lapidus
机构：
[1] Russian Academy of Sciences,Zelinsky Institute of Organic Chemistry
来源：
Kinetics and Catalysis | 2015年 / 56卷
关键词：
synthesis gas; cobalt catalysts; Fischer–Tropsch synthesis; sodium borohydride; aliphatic hydrocarbons;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new method for the preparation of catalysts for the Fischer–Tropsch synthesis is proposed; it consists in the deposition of cobalt metal on a support at the instant of reduction from salts with a solution of NaBH4. The catalysts thus prepared are stable in air, and they do not require further high-temperature activation by hydrogen. The specific rate of CO conversion was 3.4–3.7 molCO mol-1Co h–1; the selectivity for higher hydrocarbons was up to 88 mol %, and the hydrocarbon chain growth index α was up to 0.87.
引用
收藏
页码：625 / 630
页数：5
相关论文
共 50 条
  • [1] Preparation of catalysts for the Fischer-Tropsch synthesis by the deposition of cobalt reduced with NaBH4 onto a support
    Eliseev, O. L.
    Kamorin, M. A.
    Davydov, P. E.
    Volkov, A. S.
    Kazakov, A. V.
    Lapidus, A. L.
    [J]. KINETICS AND CATALYSIS, 2015, 56 (05) : 625 - 630
  • [2] STUDIES OF THE FISCHER-TROPSCH SYNTHESIS .4. PROPERTIES OF REDUCED COBALT CATALYSTS
    ANDERSON, RB
    HALL, WK
    HOFER, LJE
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1948, 70 (07) : 2465 - 2472
  • [3] Preparation and properties of supported cobalt catalysts for Fischer-Tropsch synthesis
    vandeLoosdrecht, L
    vanderHaar, M
    vanderKraan, AM
    vanDillen, AJ
    Geus, JW
    [J]. APPLIED CATALYSIS A-GENERAL, 1997, 150 (02) : 365 - 376
  • [4] THE FISCHER-TROPSCH SYNTHESIS WITH COBALT CATALYSTS
    CRAXFORD, SR
    [J]. JOURNAL OF THE SOCIETY OF CHEMICAL INDUSTRY-LONDON, 1947, 66 (12): : 440 - 444
  • [5] EFFECT OF SUPPORT AND PROMOTER IN FISCHER TROPSCH COBALT CATALYSTS
    VISWANATHAN, B
    GOPALAKRISHNAN, R
    [J]. JOURNAL OF CATALYSIS, 1986, 99 (02) : 342 - 348
  • [6] DISPERSION, SUPPORT, AND BIMETALLIC EFFECTS IN FISCHER-TROPSCH SYNTHESIS ON COBALT CATALYSTS
    IGLESIA, E
    SOLED, SL
    FIATO, RA
    VIA, GH
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 71 - CATL
  • [7] DISPERSION, SUPPORT, AND BIMETALLIC EFFECTS IN FISCHER-TROPSCH SYNTHESIS ON COBALT CATALYSTS
    IGLESIA, E
    SOLED, SL
    FIATO, RA
    VIA, GH
    [J]. NATURAL GAS CONVERSION II, 1994, 81 : 433 - 442
  • [8] Cobalt catalysts for Fischer–Tropsch synthesis: The effect of support,precipitant and pH value
    Zhenhua Li
    Mengyao Si
    Li Xin
    Renjie Liu
    Runxue Liu
    Jing Lü
    [J]. Chinese Journal of Chemical Engineering, 2018, 26 (04) : 747 - 752
  • [9] PREPARATION AND CATALYTIC BEHAVIOR OF EGGSHELL COBALT CATALYSTS FOR THE FISCHER-TROPSCH SYNTHESIS
    SOLED, SL
    BAUMGARTNER, JE
    REYES, SC
    IGLESIA, E
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 85 - CATL
  • [10] Cobalt hybrid catalysts in Fischer-Tropsch synthesis
    Adeleke, Aliu A.
    Liu, Xinying
    Lu, Xiaojun
    Moyo, Mahluli
    Hildebrandt, Diane
    [J]. REVIEWS IN CHEMICAL ENGINEERING, 2020, 36 (04) : 437 - 457
12345