Low-cost, green synthesis of highly porous carbons derived from lotus root shell as superior performance electrode materials in supercapacitor

被引:50
|
作者
Wang, Xin [2 ,3 ]
Wang, Mengjiao [2 ,3 ]
Zhang, Xuemei [2 ,3 ]
Li, Hejun [1 ]
Guo, Xiaohui [1 ,2 ,3 ]
机构
[1] Northwestern Polytech Univ, State Key Lab Solidificat Proc, Sch Mat Sci & Engn, Xian 710069, Shaanxi, Peoples R China
[2] NW Univ Xian, Minist Educ, Key Lab Synthet & Nat Funct Mol Chem, Xian 710069, Shaanxi, Peoples R China
[3] NW Univ Xian, Coll Chem & Mat Sci, Xian 710069, Shaanxi, Peoples R China
基金
美国国家科学基金会;
关键词
Carbon; Porous; Biomass; Surface area; Capacity; HYDROTHERMAL CARBONIZATION; ACTIVATED CARBONS; SURFACE-AREA; PORE-SIZE; ENERGY; TEMPLATE; GRAPHENE; STORAGE; CAPACITANCE; NANOSHEETS;
D O I
10.1016/j.jechem.2015.10.012
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Facile production of high quality activated carbons from biomass materials has greatly triggered much attention presently. In this paper, a series of interconnected porous carbon materials from lotus root shells biomass are prepared via simple pyrolysis and followed by a KOH activation process. The prepared carbons exhibit high specific surface areas of up to 2961 m(2)/g and large pore volume similar to 1.47 cm(3)/g. In addition, the resultant porous carbons served as electrode materials in supercapacitor exhibit high specific capacitance and outstanding recycling stability and high energy density. In particular, their specific capacitance retention was almost 100% after 10500 cycles at a current density of 2 A/g. Remarkabely, the impact of the tailored specific surface areas of various carbon samples on their capacitive performances is systematically investigated. Generally, it was believed that the highly-developed porosity features (including surface areas and pore volume and pore size-distributions), together with the good conductivity of activated carbon species, play a key role in effectively improving the storage energy performances of the porous carbon electrode materials in supercapacitor. (C) 2015 Science Press and Dalian Institute of Chemical Physics. All rights reserved.
引用
收藏
页码:26 / 34
页数:9
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