Synthesis, Characterization and Crystal Structure of a Mononuclear Zinc(II) Complex Derived from 2-[(2-Propylaminoethylimino)methyl] phenol

被引：1
|
作者：
Li, Xiao-Fang [1 ]
You, Zhong-Lu [1 ]
Hou, Peng [1 ]
Zhang, Cheng-Lu [1 ]
机构：
[1] Liaoning Normal Univ, Dept Chem & Chem Engn, Dalian 116029, Peoples R China
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2010年 / 40卷 / 07期
关键词：
Schiff base; Zinc(II) complex; Hydrogen bonds; Coordination chemistry;
D O I：
10.1007/s10870-010-9696-8
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new zinc(II) complex, [Zn(C12H18N2O)Cl-2]center dot CH3CN, derived from the Schiff base ligand 2-[(2-propylaminoethylimino)methyl]phenol, has been synthesized and characterized by elemental analysis, IR spectra, and X-ray crystallography. The complex crystallizes in the orthorhombic space group Pbcn with unit cell dimensions a = 26.387(9) angstrom, b = 7.389(2) angstrom, c = 18.731(6) angstrom, V = 3,652(2) angstrom(3), Z = 8, R-1 = 0.0455 and wR(2) = 0.1143. The asymmetric unit of the compound contains a mononuclear [Zn(C12H18N2O)Cl-2] complex and an acetonitrile molecule linked together by an intermolecular N-H center dot center dot center dot N hydrogen bond. Crystal packing is stabilized by intermolecular N-H center dot center dot center dot O hydrogen bonds linking the molecules into chains along the b axis of the unit cell.
引用
收藏
页码：561 / 563
页数：3
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