Source rock characteristics of the Lower Cretaceous Abu Gabra Formation in the Muglad Basin, Sudan, and its relevance to oil generation studies

被引:68
|
作者
Makeen, Yousif M. [1 ]
Abdullah, Wan Hasiah [1 ]
Hakimi, Mohammed Hail [2 ]
Mustapha, Khairul Azlan [1 ]
机构
[1] Univ Malaya, Dept Geol, Kuala Lumpur 50603, Malaysia
[2] Taiz Univ, Fac Sci Appl, Dept Geol, Taizi 6803, Yemen
关键词
Abu Gabra source rock; Kinetics modelling; Oil-types; Kerogen pyrolysis; Muglad Basin; Sudan; GAS-CHROMATOGRAPHY; INTERIOR SUDAN; PYROLYSIS; KEROGEN; MATURATION; ASPHALTENES; SHALE; EVOLUTION; SEDIMENTS; HISTORY;
D O I
10.1016/j.marpetgeo.2014.09.018
中图分类号
P [天文学、地球科学];
学科分类号
07 ;
摘要
Organic-rich shale and claystone are present within the Lower Cretaceous Abu Gabra Formation of the Muglad Basin, representing excellent oil source rocks. The source rock potential of Abu Gabra organic-rich whole rock samples from two oilfields in the Muglad Basin was investigated using bulk and quantitative pyrolysis techniques. The analytical program included TOC, pyrolysis (SRA), pyrolysis GC, bulk kinetics, elemental analysis and kerogen microscopy. The results were used to characterize the kerogen composition and type of petroleum generated from these Abu Gabra organic-rich sediments to clarify the structural variability of the organic matter in the Abu Gabra source rock. The investigated Abu Gabra organic-rich sediments proved to contain excellent quality lacustrine kerogens. The samples have moderate to high hydrogen index (HI) values (267-837 mg HC/g rock), consistent with predominantly oil-prone Types I and II kerogen with a minor contribution of Type II-III kerogens. This is supported by the abundant liptinitic materials (i.e., lipid-rich structured algae, structureless (amorphous) alginite, and sporinite) and high atomic hydrogen-to-carbon (H/C) ratio. However, pyrolysis GC analysis proved that all the investigated Abu Gabra samples contain homogeneous Type I kerogen that produces mainly waxy oil. Bulk Kinetic experiments on these samples indicate that the source rock facies derived from a homogenous organic matter, spans an extremely narrow distribution of activation energy (Ea) ranges from 49 kcal/mol to 51 kcal/mol. The magnitude order of frequency factors (A) also show a narrow distribution range from 10(12) to 10(13)/s. Based on the discrete simulated model using 3.3 degrees C/My heating rate, the average of predicted geological temperature is 0.73% Ro where the peak generation of 0.85% Ro, thus shows a typical characteristic of Type I Kerogen. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:505 / 516
页数:12
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