Bis-[3]Ferrocenophanes with Central >E-E'< Bonds (E, E'=P, SiH): Preparation, Properties, and Thermal Activation

被引：13

作者：

Isenberg, Stefan ^{[1
,2
]}

Weller, Stefan ^{[3
]}

Kargin, Denis ^{[1
,2
]}

Valic, Srecko ^{[4
]}

Schwederski, Brigitte ^{[3
]}

Kelemen, Zsolt ^{[1
,2
,5
,6
]}

Bruhn, Clemens ^{[1
,2
]}

Krekic, Kristijan ^{[1
,2
]}

Maurer, Martin ^{[1
,2
]}

Feil, Christoph M. ^{[3
]}

Nieger, Martin ^{[7
]}

Gudat, Dietrich ^{[3
]}

Nyulaszi, Laszlo ^{[5
,6
]}

Pietschnig, Rudolf ^{[1
,2
]}

机构：

[1] Univ Kassel, Inst Chem, Heinrich Plett Str 40, D-34132 Kassel, Germany

[2] Univ Kassel, CINSaT, Heinrich Plett Str 40, D-34132 Kassel, Germany

[3] Univ Stuttgart, Inst Inorgan Chem, Pfaffenwaldring 55, D-70550 Stuttgart, Germany

[4] Rudjer Boskovic Inst, Bijenicka Cesta 54, Zagreb 10000, Croatia

[5] Budapest Univ Technol & Econ, Dept Inorgan & Analyt Chem, Szent Gellert Ter 4, H-1111 Budapest, Hungary

[6] Budapest Univ Technol & Econ, MTA BME Computat Driven Chem Res Grp, Szent Gellert Ter 4, H-1111 Budapest, Hungary

[7] Univ Helsinki, Dept Chem, POB 55, Helsinki 00014, Finland

来源：

CHEMISTRYOPEN | 2019年 / 8卷 / 10期

关键词：

phosphorus; ferrocene; homolytic bond cleavage; thermolysis; radicals; PERSISTENT PHOSPHINYL; X-RAY; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; PHOSPHORUS; RADICALS; ELECTROCHEMISTRY; DERIVATIVES; REDUCTION; ELEMENTS;

D O I：

10.1002/open.201900182

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Invited for this month's cover picture are the groups of Professors Rudolf Pietschnig at the University of Kassel, Professor Dietrich Gudat at the University of Stuttgart and Professor Laszlo Nyulaszi at the Budapest University of Technology and Economics. The cover picture shows the thermally induced homolytic cleavage of the central P-P bond in a phosphorus-rich bis-ferrocenophane furnishing P-centered radicals (as evidenced by the computed spin-density highlighted in blue). The central P-6 unit in the title compound is a structural analog of the connecting unit in Hittorf's violet phosphorus, which links the orthogonally arranged tubular entities. A portrait of the German physicist Johann Wilhelm Hittorf is included. Read the full text of their Full Paper at 10.1002/open.201900182.

引用

页码：1235 / 1243

页数：9

共 50 条

[21] Solution Phase Reactivity of Dibenzo[c,e][1,2]azaborinine: Activation and Insertion into Si-E Single Bonds (E= H, OSi (CH3)3, F, Cl) by a BN-Aryne
Keck, Constanze
Hahn, Jennifer
Gupta, Divanshu
Bettinger, Holger F.
CHEMISTRY-A EUROPEAN JOURNAL, 2022, 28 (05)
[22] Solution Phase Reactivity of Dibenzo[c,e][1,2]azaborinine: Activation and Insertion into Si-E Single Bonds (E=H, OSi(CH3)3, F, Cl) by a BN-Aryne
Keck, Constanze
Hahn, Jennifer
Gupta, Divanshu
Bettinger, Holger F.
CHEMISTRY-A EUROPEAN JOURNAL, 2021,
[23] SYNTHESIS, STRUCTURE, AND PROPERTIES OF THE [E(7)M(CO)(3)](3-) COMPLEXES WHERE E=P, AS, SB AND M=CR, MO, W
CHARLES, S
EICHHORN, BW
RHEINGOLD, AL
BOTT, SG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (18) : 8077 - 8086
[24] STRUCTURAL AND CATALYTIC PROPERTIES OF GLYCERALDEHYDE-3-P DEHYDROGENASE OF E COLI
DALESSIO, G
FEDERATION PROCEEDINGS, 1969, 28 (02) : 848 - &
[25] Synthesis and Characterization of Tetraoxime Ligand, Bis-[(2E,3E,2′E)-3,3′-(1,2-Phenylene-Dinitrilo)dibutan-2-One Dioxime] and Its Dinuclear and Tetranuclear Copper(II)/Nickel(II) Complexes
Karaboecek, Nevin
Ekmekcioglu, Pmar
Kuecuekdumlu, Asliguel
Karaboecek, Serdar
TURKISH JOURNAL OF CHEMISTRY, 2009, 33 (01) : 99 - 106
[26] MEASUREMENT OF THE R(LT), R(L), AND R(T) RESPONSE FUNCTIONS FOR THE HE-4(E,E'P)H-3 REACTION AT LARGE MISSING MOMENTUM
EPSTEIN, MB
ANIOL, KA
MARGAZIOTIS, DJ
JIANG, B
BAGHAEI, H
BERTOZZI, W
BOEGLIN, W
WEINSTEIN, L
PENN, S
MORRISON, J
LOURIE, RW
FINN, JM
PERDRISAT, CF
PUNJABI, V
ULMER, PE
CHANG, CC
BOBERG, P
CALARCO, J
LAGET, JM
PHYSICAL REVIEW LETTERS, 1993, 70 (19) : 2868 - 2871
[27] Synthesis and photochromic properties of E,E-Bis-α-(2,5-dimethyl-3-furyl)ethylide anhydride and its 2-dicyanomethylene derivative
Asiri, AM
KUWAIT JOURNAL OF SCIENCE & ENGINEERING, 1999, 26 (02): : 283 - 288
[28] BIS(TRIFLUOROMETHYLCHALCOGENYL)KETENES (CF3E)2C=C=O (E = S, SE, SO2) - SYNTHESIS AND PROPERTIES
HAAS, A
PRAAS, HW
CHEMISCHE BERICHTE-RECUEIL, 1992, 125 (03): : 571 - 579
[29] MCl2 Molecules (M = Zn, Cd, Hg) Coordinated by Trifunctional E/P2-Based FLPs (E = Ga, In): Chelating Coordination of the Metal Atoms and Activation of M-Cl Bonds by E-Cl Interactions
Uebing, Marten
Hepp, Alexander
Uhl, Werner
ORGANOMETALLICS, 2020, 39 (14) : 2695 - 2704
[30] Reactive E=C(p-p)π-systems.: 56 -: Attempted preparation of PhE=C(CF3)2 by reactions of hexafluoroacetone with PhE(SiMe3)2 (E = As, P)
Albers, T
Grobe, J
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (12): : 2393 - 2396

← 1 2 3 4 5 →

Bis-[3]Ferrocenophanes with Central &gt;E-E'&lt; Bonds (E, E'=P, SiH): Preparation, Properties, and Thermal Activation

Bis-[3]Ferrocenophanes with Central >E-E'< Bonds (E, E'=P, SiH): Preparation, Properties, and Thermal Activation