Bis-[3]Ferrocenophanes with Central >E-E'< Bonds (E, E'=P, SiH): Preparation, Properties, and Thermal Activation

被引：13

作者：

Isenberg, Stefan ^{[1
,2
]}

Weller, Stefan ^{[3
]}

Kargin, Denis ^{[1
,2
]}

Valic, Srecko ^{[4
]}

Schwederski, Brigitte ^{[3
]}

Kelemen, Zsolt ^{[1
,2
,5
,6
]}

Bruhn, Clemens ^{[1
,2
]}

Krekic, Kristijan ^{[1
,2
]}

Maurer, Martin ^{[1
,2
]}

Feil, Christoph M. ^{[3
]}

Nieger, Martin ^{[7
]}

Gudat, Dietrich ^{[3
]}

Nyulaszi, Laszlo ^{[5
,6
]}

Pietschnig, Rudolf ^{[1
,2
]}

机构：

[1] Univ Kassel, Inst Chem, Heinrich Plett Str 40, D-34132 Kassel, Germany

[2] Univ Kassel, CINSaT, Heinrich Plett Str 40, D-34132 Kassel, Germany

[3] Univ Stuttgart, Inst Inorgan Chem, Pfaffenwaldring 55, D-70550 Stuttgart, Germany

[4] Rudjer Boskovic Inst, Bijenicka Cesta 54, Zagreb 10000, Croatia

[5] Budapest Univ Technol & Econ, Dept Inorgan & Analyt Chem, Szent Gellert Ter 4, H-1111 Budapest, Hungary

[6] Budapest Univ Technol & Econ, MTA BME Computat Driven Chem Res Grp, Szent Gellert Ter 4, H-1111 Budapest, Hungary

[7] Univ Helsinki, Dept Chem, POB 55, Helsinki 00014, Finland

来源：

CHEMISTRYOPEN | 2019年 / 8卷 / 10期

关键词：

phosphorus; ferrocene; homolytic bond cleavage; thermolysis; radicals; PERSISTENT PHOSPHINYL; X-RAY; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; PHOSPHORUS; RADICALS; ELECTROCHEMISTRY; DERIVATIVES; REDUCTION; ELEMENTS;

D O I：

10.1002/open.201900182

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Invited for this month's cover picture are the groups of Professors Rudolf Pietschnig at the University of Kassel, Professor Dietrich Gudat at the University of Stuttgart and Professor Laszlo Nyulaszi at the Budapest University of Technology and Economics. The cover picture shows the thermally induced homolytic cleavage of the central P-P bond in a phosphorus-rich bis-ferrocenophane furnishing P-centered radicals (as evidenced by the computed spin-density highlighted in blue). The central P-6 unit in the title compound is a structural analog of the connecting unit in Hittorf's violet phosphorus, which links the orthogonally arranged tubular entities. A portrait of the German physicist Johann Wilhelm Hittorf is included. Read the full text of their Full Paper at 10.1002/open.201900182.

引用

页码：1235 / 1243

页数：9

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Bis-[3]Ferrocenophanes with Central &gt;E-E'&lt; Bonds (E, E'=P, SiH): Preparation, Properties, and Thermal Activation

Bis-[3]Ferrocenophanes with Central >E-E'< Bonds (E, E'=P, SiH): Preparation, Properties, and Thermal Activation