Thermal Properties and Chemical Changes in Blend Melt Spinning of Cellulose Acetate Butyrate and a Novel Cationic Dyeable Copolyester

被引：20
|
作者：
Chen, Bin [1 ]
Zhong, Leilan [1 ]
Gu, Lixia [1 ]
机构：
[1] Donghua Univ, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2010年 / 116卷 / 05期
关键词：
copolyester; cellulose acetate butyrate; fiber; blend melt spinning; BACTERIAL POLY(3-HYDROXYBUTYRATE); CRYSTALLIZATION; BEHAVIOR; POLY(ETHYLENE-TEREPHTHALATE); MISCIBILITY; COPOLYMER;
D O I：
10.1002/app.30984
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A novel cationic dyeable copolyester (MCDP) containing purified terephthalate acid (PIA), ethylene glycol (EG), 2-methyl-1,3-propanediol (MPD), and sodium-5-sulfo-isophthalate (SIP) was synthesized via direct esterification method. The chemical structure of modified cationic dyeable polyester (MCPD) was confirmed by FTIR and H-1-NMR. The thermal properties of MCDP and cellulose acetate butyrate (CAB) blends with different blend ratios were investigated by DSC. The results revealed that MCDP and CAB were immiscible polymer blends, and the glass transition temperature of CAB in blend fibers was higher than that of CAB in blend chips because of the strengthening hydrogen bonding. The chemical changes of MCDP and CAB in blend melt spinning were analyzed. It was found that the thermal hydrolysis reaction of ester side groups of CAB occurred in blend melt spinning, which resulted in that the acid gas was produced and the hydroxyl group content of CAB was increased. Furthermore, the moisture absorption of blend fibers was improved about three times than pure MCDP fiber even after washing 30 times. (c) 2010 Wiley Periodicals, Inc. J Appl Polym Sci 116: 2487-2495, 2010
引用
收藏
页码：2487 / 2495
页数：9
相关论文
共 36 条
  • [31] Novel Bionanocomposites Containing Green Synthesized Silver NPs of a Carboxymethyl Cellulose-Based Blend; Thermal, Optical, Biological and Dielectric Properties
    Merve Sivrier
    Ömer Hazman
    Sanjar Tillayev
    Ibrahim Erol
    Journal of Polymers and the Environment, 2023, 31 : 3857 - 3874
  • [32] Study on the effect of m-phenylenediamine as a cross-linking agent on the mechanical, chemical and thermal properties and performance of cellulose acetate/nanodiamond membranes
    Haleh Nourizadeh Kazerouni
    Yoones Jafarzadeh
    Reza Yegani
    Polymer Bulletin, 2020, 77 : 405 - 425
  • [33] Study on the effect of m-phenylenediamine as a cross-linking agent on the mechanical, chemical and thermal properties and performance of cellulose acetate/nanodiamond membranes
    Nourizadeh Kazerouni, Haleh
    Jafarzadeh, Yoones
    Yegani, Reza
    POLYMER BULLETIN, 2020, 77 (01) : 405 - 425
  • [34] Effect of cellulose acetate butyrate microencapsulated ammonium polyphosphate on the flame retardancy, mechanical, electrical, and thermal properties of intumescent flame-retardant EVA/MCAPP/PA-6 blends
    Wang, Bibo
    Hu, Yuan
    Song, Lei
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
  • [35] Effect of Cellulose Acetate Butyrate Microencapsulated Ammonium Polyphosphate on the Flame Retardancy, Mechanical, Electrical, and Thermal Properties of Intumescent Flame-Retardant Ethylene-Vinyl Acetate Copolymer/Microencapsulated Ammonium Polyphosphate/Polyamide-6 Blends
    Wang, Bibo
    Tang, Qinbo
    Hong, Ningning
    Song, Lei
    Wang, Lei
    Shi, Yongqian
    Hu, Yuan
    ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (09) : 3754 - 3761
  • [36] Chemical and Thermal Properties of Cellulose Acetate Prepared from White Willow (Salix alba) and Black Alder (Alnus glutinosa) as a Potential Polymeric Base of Biocomposite Materials
    Spanic, N.
    Jambrekovic, V.
    Medved, S.
    Antonovic, A.
    CHEMICAL AND BIOCHEMICAL ENGINEERING QUARTERLY, 2015, 29 (03) : 357 - 365
1234