The Preparation and Characterization of Some Novel Quaternary Iminium Salts Based on Schiff-base as a Corrosion Inhibitor

被引：32
|
作者：
El-Sukkary, M. M. A. [1 ]
Aiad, I. [1 ]
Deeb, A. [2 ]
El-Awady, M. Y. [1 ]
Ahmed, H. M. [1 ]
Shaban, S. M. [1 ]
机构：
[1] Egyptian Petr Res Inst, Nasr City 11727, Cairo, Egypt
[2] Zagazig Univ, Fac Sci, Dept Chem, Zagazig, Egypt
来源：
PETROLEUM SCIENCE AND TECHNOLOGY | 2010年 / 28卷 / 11期
关键词：
cationic surfactants; corrosion inhibitors; quaternary iminium salts; surface parameters; THERMODYNAMIC PROPERTIES; SURFACE; MICELLIZATION; MICELLES;
D O I：
10.1080/10916460902967718
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Novel quaternary iminium compounds, namely, N-(4-methoxybenzylidene)-N-benzyldodecyliminium chloride (Ia), N-(4-methoxybenzylidene)-N-benzylhexadecyl iminium chloride (Ib), N-(4-methoxybenzylidene)-N-benzyloctadecyliminium chloride (Ic), and N-benzylidene-N-benzyldodecyliminium chloride, were prepared. The surface properties such as surface and interfacial tension, foaming, and emulsifying power of these surfactants were investigated. The surface parameters including critical micelle concentration (CMC), maximum surface excess (max), minimum surface area (Amin), efficiency (PC20), and effectiveness (CMC) were calculated. Free energy of micellization (G degrees mic) and adsorption (G degrees ads) were calculated.
引用
收藏
页码：1158 / 1169
页数：12
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