Octahedral Chalcogenide Rhenium Clusters: From Solids to Isolated Cluster Complexes

被引：12
|
作者：
Fedorov, Vladimir E. [1 ,2 ]
Naumov, Nikolay G. [1 ,2 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk, Russia
来源：
LIGATED TRANSITION METAL CLUSTERS IN SOLID-STATE CHEMISTRY: THE LEGACY OF MARCEL SERGENT | 2019年 / 180卷
关键词：
Cluster; Complex; Crystal structure; Luminescence; Molybdenum; Rhenium; Solid state; PARAMAGNETIC-RESONANCE PARAMETERS; MOLECULAR BUILDING-BLOCKS; SUPER-PRUSSIAN-BLUE; METAL ATOM CLUSTERS; BRIDGED RE(6)Q(8) Q; CRYSTAL-STRUCTURES; THERMOELECTRIC PROPERTIES; BIOCTAHEDRAL CLUSTER; DFT CALCULATIONS; CHEVREL-PHASE;
D O I：
10.1007/430_2019_33
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This review summarizes the numerous studies on the chemistry of molybdenum and rhenium octahedral chalcogenide cluster compounds carried out over the years at the Nikolaev Institute of Inorganic Chemistry in collaboration with international research groups. A pathway from classical solid-state cluster compounds Mo6Se8, Re6Te15, and K4Re6S12, influenced by the French school of solid-state cluster chemistry, to soluble molecular complexes with Re(6)Q(8) and Mo(6)Q(8) cluster cores is provided. Both inorganic and organic ligands can be grafted onto cluster cages, resulting in a drastic change in the charge and properties of such complexes.
引用
收藏
页码：31 / 74
页数：44
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