Octahedral Chalcogenide Rhenium Clusters: From Solids to Isolated Cluster Complexes

被引：12

作者：

Fedorov, Vladimir E. ^{[1
,2
]}

Naumov, Nikolay G. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia

[2] Novosibirsk State Univ, Novosibirsk, Russia

来源：

LIGATED TRANSITION METAL CLUSTERS IN SOLID-STATE CHEMISTRY: THE LEGACY OF MARCEL SERGENT | 2019年 / 180卷

关键词：

Cluster; Complex; Crystal structure; Luminescence; Molybdenum; Rhenium; Solid state; PARAMAGNETIC-RESONANCE PARAMETERS; MOLECULAR BUILDING-BLOCKS; SUPER-PRUSSIAN-BLUE; METAL ATOM CLUSTERS; BRIDGED RE(6)Q(8) Q; CRYSTAL-STRUCTURES; THERMOELECTRIC PROPERTIES; BIOCTAHEDRAL CLUSTER; DFT CALCULATIONS; CHEVREL-PHASE;

D O I：

10.1007/430_2019_33

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review summarizes the numerous studies on the chemistry of molybdenum and rhenium octahedral chalcogenide cluster compounds carried out over the years at the Nikolaev Institute of Inorganic Chemistry in collaboration with international research groups. A pathway from classical solid-state cluster compounds Mo6Se8, Re6Te15, and K4Re6S12, influenced by the French school of solid-state cluster chemistry, to soluble molecular complexes with Re(6)Q(8) and Mo(6)Q(8) cluster cores is provided. Both inorganic and organic ligands can be grafted onto cluster cages, resulting in a drastic change in the charge and properties of such complexes.

引用

页码：31 / 74

页数：44

共 50 条

[1] Octahedral chalcogenide rhenium cluster complexes with imidazole
Konovalov, Dmitry, I
Ivanov, Anton A.
Vorotnikov, Yuri A.
Smolentsev, Anton, I
Eltsov, Ilia, V
Efremov, Olga A.
Kitamura, Noboru
Mironov, Yuri, V
Shestopalov, Michael A.
POLYHEDRON, 2019, 165 : 79 - 85
[2] RHENIUM OCTAHEDRAL CHALCOHYDROXO CLUSTER COMPLEXES
Mironov, Y. V.
Yarovoi, S. S.
Brylev, K. A.
Fedorov, V. E.
7TH INTERNATIONAL SYMPOSIUM ON TECHNETIUM AND RHENIUM - SCIENCE AND UTILIZATION, 2011, : 27 - 27
[3] OCTAHEDRAL RHENIUM(III) CHALCOCYANOHYDROXO CLUSTER COMPLEXES
Ermolaev, A. V.
Smolentsev, A. I.
Brylev, K. A.
Fedorov, V. E.
Mironov, Y. V.
7TH INTERNATIONAL SYMPOSIUM ON TECHNETIUM AND RHENIUM - SCIENCE AND UTILIZATION, 2011, : 74 - 74
[4] Cellular uptake and cytotoxicity of octahedral rhenium cluster complexes
Choi, Soo Jin
Brylev, Konstantin A.
Xu, Jing-Zhe
Mironov, Yuri V.
Fedorov, Vladimir E.
Sohn, Youn Soo
Kim, Sung Jin
Choy, Jin-Ho
JOURNAL OF INORGANIC BIOCHEMISTRY, 2008, 102 (11) : 1991 - 1996
[5] Chalcogenide Cluster Complexes of Chromium, Molybdenum, Tungsten, and Rhenium
Saito, T.
Imoto, H.
Bulletin of the Chemical Society of Japan, 69 (09):
[6] Chalcogenide cluster complexes of chromium, molybdenum, tungsten, and rhenium
Saito, T
Imoto, H
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1996, 69 (09) : 2403 - 2417
[7] CHEMISTRY OF OCTAHEDRAL RHENIUM CLUSTERS
CHEN, S
MORRIS, BJ
ROBINSON, WR
ACS SYMPOSIUM SERIES, 1983, 211 : 527 - 527
[8] Complexes based on the anionic octahedral rhenium chalcogenide clusters and [M(En)2]2+ (M = Ni, Cu) cations
Mironov, Y. V.
Yarovoi, S. S.
Ermolaev, A. V.
Brylev, K. A.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2012, 38 (04) : 264 - 272
[9] Complexes based on the anionic octahedral rhenium chalcogenide clusters and [M(En)2]2+ (M = Ni, Cu) cations
Y. V. Mironov
S. S. Yarovoi
A. V. Ermolaev
K. A. Brylev
Russian Journal of Coordination Chemistry, 2012, 38 : 264 - 272
[10] Apically homoleptic octahedral rhenium cluster complexes with 3-methylpyrazole
Konovalov, Dmitry I.
Ivanov, Anton A.
Vorotnikov, Yuri A.
Brylev, Konstantin A.
Eltsov, Ilia V.
Yanshole, Vadim V.
Kuratieva, Natalia V.
Kitamura, Noboru
Shestopalov, Michael A.
INORGANICA CHIMICA ACTA, 2020, 510

← 1 2 3 4 5 →