Crystal Structure of A Molecular Complex Compound of Antimony(III) Fluoride with L-Leucine

被引:12
|
作者
Udovenko, A. A. [1 ]
Makarenko, N. V. [1 ]
Davidovich, R. L. [1 ]
Zemnukhova, L. A. [1 ]
Kovaleva, E. V. [1 ]
机构
[1] Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia
关键词
single crystal X-ray diffraction analysis; crystal structure; antimony(III) fluoride; L-leucine; molecular complex compound;
D O I
10.1007/s10947-010-0113-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Single crystal X-ray diffraction analysis is used to determine the crystal structure of a newly synthesized molecular complex compound of antimony(III) fluoride with L-leucine of the composition SbF(3)(C6H(13)NO(2)) (orthohombic crystal system: a = 5.7948(8) , b = 6.2433(9) , c = 28.594(4) , Z = 4, P2(1)2(1)2(1) space group). The structure consists of SbF(3) molecules and L-leucine bound into polymer chains by bidentate bridging carboxyl groups of amino acid molecules. Weak SbaEuro broken vertical bar F(1)(b) bonds combine the adjacent chains into polymer ribbons organized by N-HaEuro broken vertical bar. F and N-HaEuro broken vertical bar. O hydrogen bonds into a framework.
引用
收藏
页码:765 / 768
页数:4
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