Inner-valence Auger decay in chloroform after Cl 2p ionization

被引：3

作者：

Vasconcelos, D. N. ^{[1
]}

MacDonald, M. A. ^{[2
]}

Tenorio, B. N. C. ^{[3
]}

Sant'Anna, M. M. ^{[1
]}

Rocha, A. B. ^{[3
]}

Morcelle, V. ^{[4
]}

Bonfim, V. S. ^{[1
]}

Appathurai, N. ^{[2
]}

Zuin, L. ^{[2
]}

Santos, A. C. F. ^{[1
]}

机构：

[1] Univ Fed Rio de Janeiro, Inst Fis, BR-21941972 Rio De Janeiro, RJ, Brazil

[2] Canadian Light Source Inc, Saskatoon, SK S7N 2V3, Canada

[3] Univ Fed Rio de Janeiro, Inst Quim, BR-21941909 Rio De Janeiro, RJ, Brazil

[4] Univ Fed Rural Rio de Janeiro, Dept Fis, BR-23890000 Rio De Janeiro, RJ, Brazil

来源：

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS | 2019年 / 461卷

基金：

加拿大健康研究院; 加拿大自然科学与工程研究理事会; 加拿大创新基金会;

关键词：

Auger decay; Chloroform; Density functional theory; MASS-SPECTROMETRY;

D O I：

10.1016/j.nimb.2019.09.039

中图分类号：

TH7 [仪器、仪表];

学科分类号：

0804 ; 080401 ; 081102 ;

摘要：

The inner-valence Auger electron spectra after the chlorine 2p ionization in the gas phase CHCl3 molecule were investigated both theoretically and experimentally. The total ion yield spectrum exhibits a broad structure at 217 eV, above the Cl 2p ionization threshold, which can be attributed to either a shape resonance or a shake-up. In addition, we have performed a series of high-level ab initio quantum mechanical calculations at the density functional theory level to compute the Auger lines.

引用

页码：133 / 136

页数：4

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