Catalyst-Free Visible Light Mediated Synthesis of Unsymmetrical Tertiary Arylphosphines

被引：9
|
作者：
Bugaenko, Dmitry I. [1 ]
Karchava, Alexander V. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119234, Russia
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2022年 / 364卷 / 13期
基金：
俄罗斯科学基金会;
关键词：
Phosphanes; Diaryliodonium salts; Photochemistry; Hypervalent compounds; Synthetic methods; C-P(III) BOND FORMATION; DIARYLIODONIUM SALTS; PHOSPHONIUM SALTS; ARYL; PHOSPHINES; ARYLATION; TRIARYLPHOSPHINES;
D O I：
10.1002/adsc.202200309
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Arylation of tertiary aryl and alkyl phosphines bearing 2-cyanoethyl group with aryl(mesityl)iodonium triflates under blue light irradiation followed by retro-Michael reaction of the in situ generated quaternary phosphonium salts initiated by DBU represent a novel efficient and general method for the preparation of distinctly substituted tertiary arylphosphines. An operationally simple, one-pot protocol features mild, transition-metal-free conditions, high selectivity, broad functional group compatibility, as well as scalability and would be applied to substrates with different electronic and steric nature.
引用
收藏
页码：2248 / 2253
页数：6
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