Ag3SnP7:: A polyphosphide with a unique ∞1(P7) chain and a novel Ag3Sn heterocluster

被引：0

作者：

Shatruk, MM ^{[1
]}

Kovnir, KA ^{[1
]}

Shevelkov, AV ^{[1
]}

Popovkin, BA ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Inorgan Synth Lab, Moscow 119899, Russia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2000年 / 39卷 / 14期

关键词：

cluster compounds; polyphosphides; silver; solid-state structures; tin;

D O I：

10.1002/1521-3773(20000717)39:14<2508::AID-ANIE2508>3.0.CO;2-O

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new structural fragments are present in the crystal structure of the polyphosphide Ag3SnP3: infinite one-dimensional (∞)/1(P7) chains and Ag7Sn tetrahedra (see picture), which interlink the chains and represent a rare example of transition/post-transition metal heteroclusters in a polyphosphide structure.

引用

页码：2508 / +

页数：3

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