Synthesis and characterization of MCM-22 zeolites for the N2O oxidation of benzene to phenol

被引：0
|
作者：
Meloni, D
Monaci, R
Rombi, E
Guimon, C
Martinez, H
Fechete, I
Dumitriu, E
机构：
[1] Univ Cagliari, Complesso Univ Monserrato, Dipartimento Sci Chim, I-09042 Cagliari, Italy
[2] CNRS, UMR 5624, Lab Physicochim Mol, F-64000 Pau, France
[3] Tech Univ Iasi, Catalysis Lab, Iasi 6600, Romania
来源：
IMPACT OF ZEOLITES AND OTHER POROUS MATERIALS ON THE NEW TECHNOLOGIES AT THE BEGINNING OF THE NEW MILLENNIUM, PTS A AND B | 2002年 / 142卷
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D O I：
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中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
MCM-22 zeolites with various Si/Al and/or Si/Fe ratios were synthesized and characterized by XRD, microcalorimetry and other techniques. The catalytic activity and selectivity of MCM-22 zeolites were investigated in the gas-phase oxidation of benzene with N2O at 673 K. The oxidation of benzene produces phenol as main product. The influence of the nature of catalysts (i.e., the content of iron, the nature of active sites) on catalytic activity of MCM-22 was investigated. In addition, some results about the nature of coke, which causes the Fe-MCM-22 deactivation, are exposed.
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页码：167 / 174
页数：8
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