Photocatalytic degradation of Rhodamine B on TiO2 nanoparticles modified with porphyrin and iron-porphyrin

被引:79
|
作者
Huang, Heyong [1 ,2 ]
Gu, Xiaotian [2 ]
Zhou, Jiahong [1 ,2 ]
Ji, Kang [2 ]
Liu, Hailong [2 ]
Feng, Yuying [1 ,2 ]
机构
[1] Key Lab Biofunct Mat Jiangsu Prov, Nanjing 210097, Peoples R China
[2] Nanjing Normal Univ, Anal & Testing Ctr, Dept Chem & Environm Sci, Nanjing 210097, Peoples R China
关键词
Porphyrin; Fe(III) porphyrin; TiO2; Photocatalytic degradation; Rhodamine B; AQUEOUS SUSPENSION; 4-NITROPHENOL; POLLUTANTS; OXIDATION; EPR;
D O I
10.1016/j.catcom.2009.08.012
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The photocatalytic degradation of Rhodamine B(RhB) on TiO2 nanoparticle modified with porphyrin (Pr) and Fe(III)porphyrin (Fe(III)Pr), which were prepared through the chemisorption method, have been investigated under ultraviolet light and visible light irradiation. The results indicated that the photodegradation of RhB was significantly enhanced in the presence of the Pr/TiO2 or Fe(III)Pr/TiO2 comparing with the nonmodified TiO2 under ultraviolet light, but under visible light. only Pr/TiO2 has remarkable effect. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:58 / 61
页数:4
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