Sulfination of alcohols with sodium sulfinates promoted by BF3•OEt2: an unexpected access

被引：46

作者：

Huang, Mingming ^{[1
]}

Hu, Liangzhen ^{[1
]}

Shen, Hang ^{[1
]}

Liu, Qing ^{[1
]}

Hussain, Muhammad Ijaz ^{[1
]}

Pan, Jing ^{[1
]}

Xiong, Yan ^{[1
,2
]}

机构：

[1] Chongqing Univ, Sch Chem & Chem Engn, Chongqing 400030, Peoples R China

[2] Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China

来源：

GREEN CHEMISTRY | 2016年 / 18卷 / 07期

关键词：

NUCLEOPHILIC-SUBSTITUTION; ALLYLIC SUBSTITUTION; BENZYL ALCOHOLS; BOND FORMATION; LIGNIN MODELS; ETHERS; SULFONES; ESTERS; SALTS; SULFONYLATION;

D O I：

10.1039/c5gc02846a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A BF3 center dot OEt2-promoted direct substitution of various alcohols with sodium sulfinates affording sulfinates under mild conditions has been developed. Further reaction of the hydroxysteroids achieves the highly complex sulfinates in good yields, which are two potential pharmacophores routinely encountered in drug discovery.

引用

页码：1874 / 1879

页数：6

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