Application of derivative spectrophotometry to simultaneous determination of nickel and mercury with diethylenetriaminepentaacetic acid (DTPA)

被引:4
|
作者
PerezIglesias, J
SecoLago, H
FernandezSolis, JM
CastroRomero, JM
GonzalezRodriguez, V
机构
[1] Department of Analytical Chemistry, Univ. School Polytechnic of Ferrol, University of La Coruña
关键词
nickel determination; mercury determination; derivative spectrophotometry; DTPA; simultaneous determination;
D O I
10.1080/00032719708002805
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The application of derivative spectrophotometry to the simultaneous determination of nickel(II) and mercury(II) with diethylenetriaminepentaacetic acid (DTPA) is described. The procedure doesn't require equations to be solved, and it is suitable for concentrations of 0.40-1.80 mg ml(-1) of nickel and 0.20-0.70 mg ml(-1) of mercury. The main interferences, both anionic and cationic, are easily eliminated. The method was applied to different aqueous matrices and it was compared with an atomic absorption (AA) method. Good results were obtained.
引用
收藏
页码:317 / 325
页数:9
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