Particular Handedness Excess through Symmetry-Breaking Crystallization of a 3D Cobalt Phosphonate

被引：18

作者：

Gao, Chao-Ying ^{[1
,3
]}

Wang, Fei ^{[2
]}

Tian, Hong-Rui ^{[1
]}

Li, Lei-Jiao ^{[1
]}

Zhang, Jian ^{[2
]}

Sun, Zhong-Ming ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, 5625 Renmin St, Changchun 130022, Jilin, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

来源：

INORGANIC CHEMISTRY | 2016年 / 55卷 / 02期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORKS; CHIRAL POROUS SOLIDS; SPONTANEOUS RESOLUTION; COORDINATION POLYMERS; ABSOLUTE HELICITY; ACHIRAL LIGANDS; SINGLE-CRYSTAL; INDUCTION; ACID; POLYMORPHISM;

D O I：

10.1021/acs.inorgchem.5b02187

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 3D chiral cobalt phosphonate has been obtained from achiral precursors in the absence of chiral inducers. Remarkably, the bulk sample is largely enantio-enriched with particular handedness through symmetry-breaking crystallization in spite of multiple repeated experiments. Moreover, protonation of this chiral material introduces Bronsted acid sites, the structure of which is unique to the heterogeneous phase for the ring opening of epoxies.

引用

页码：537 / 539

页数：3

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